By Marco Stoppaccioli

In today´s society, due to higher life expectancy, greater and more responsible attention to one´s body, we have developed a culture more sensitive to personal well-being. Consequently, more patients with total removable prostheses request stabilization of their prostheses through implant treatment which offers the most effective and valid response to this need.

The demand for implant treatments has increased significantly during the last decade, specifically from patients with long-term full prostheses resulting in considerable bone resorption¹, but are hesitant to undergo complex bone regeneration interventions (Photo 1).

These rehabilitations require great commitment and professional skills. In addition to restoring a complex series of aesthetic-functional parameters that have been lost. Innovative products were developed, not only the restoration of the dental, but also, the orthopedic aspects of the procedure.

Photo 1: Upper and lower Jaw situation models.

Initially, the dental-skeletal rehabilitations involved the exclusive use of metal posts combined with acrylic materials.

In recent decades, we have witnessed an evolution in the surgical techniques and materials used, among these, zirconia² has a significant and highly innovative role. The main reason for its success is due to the possibility of being able to use it anatomically through a simple and effective protocol thanks to CAD CAM technology.

Zirconia, created to be covered with ceramic coatings, has undergone a profound evolution: from an exclusively structural material with high strength but low aesthetic appeal, it has become anatomical, constituting an alternative to layered restorations. Thanks to research and innovation, optimizing chemical and physical parameters³ in the dental industry, we now have a wide range of products, including multi-layer zirconia.

In more analytical terms, it offers a very valid response to the translucency, which is inversely proportional to the flexural strength. On the market this material class oscillates between 550Mpa and 1200Mpa of flexural strength. This characteristic identifies its indication range, specifically depending on the yttrium oxide content, which acts as a stabilizer of zirconia.

For dental-skeletal rehabilitations, the protocol involves the use of multi-layer monolithic zirconia with marked characteristics of flexural strength but lower translucency which determines a limit in the aesthetic sense. On the other hand, the use of multi-layered zirconia with high translucency cannot be considered suitable, due to its lack of flexural strength, despite fully meeting the requirement for naturalness.

To date it can be said that there is no zirconia that offers high mechanical properties combined with high translucency, two fundamental aspects for successful restorations.

Considering these factors, the idea was born to generate an innovative and experimental protocol capable of supporting, on the one hand, the ability of CAD/CAM systems to copy exactly a project or even better, a functionalized provisional implant, and on the other, to associate the use of two zirconia with different characteristics: one extremely tough, white colored zirconia with 1125 MPa (KATANA™ HT Kuraray Noritake) and the other super translucent multi-layered zirconia with 750 MPa (KATANA™ STML Kuraray Noritake).

OPERATIONAL PROTOCOL

In dental-skeletal rehabilitations, success depends on a precise diagnosis by the clinician, aimed at the functional and aesthetic restoration of the case. It is a fundamental task of the dental technician to translate this information through the creation of a wax-up, both analog and digital.

Photo 2: Digital wax-up.

Photo 3: Analog wax-up.

Thanks to digitization, with a 3D printer, it is possible to realize the wax-up quickly and economically in a prototype, capable of allowing the clinician to perform an initial test in the oral cavity.

Photo 4: From design to 3D prototype.

Once the adequacy of the prototype under study has been certified, the next phase involves the construction of the provisional implant which, placed in the oral cavity for a specified time, provides the fundamental information from an occlusal point of view, both in static and dynamic conditions.

The first strength of this protocol is to capture all information about the provisional implant and transfer them to the final work through digital systems. In other words, the provisional implant itself becomes the design of the final product.

Photo 5: Temporary result of analog project.

Photo 6: Acquisition of temporary arches refitted on the models.

FINAL PROCEDURE: OPERATING PHASES

Once the scans of the temporary implant have been acquired in the digital platform, the structural frame obtained by reduction of the temporary implant file is generated. The framework will be made by using KATANA™ HT white colored zirconia (Kuraray Noritake Dental Inc.) with a flexural strength of 1125 MPa. This choice is attributable to an adequate toughness of the material and an effective aesthetic chromatic response on the pink ceramic coating.

Photo 7: Structural framework.

Photo 8: White zirconia framework, 1125 MPa (KATANA HT).

Once the structural file is generated, it is called up within the modeling software to create the anatomical components that will be divided into quadrants.

Photo 9: File divided into three seqments.

The selected material is multi-layered KATANA™ Zirconia STML by Kuraray Noritake Dental Inc. with a flexural strength of 750 MPa and high translucency. KATANA™ Zirconia STML shows an optimized balance between mechanical and optical characteristics.

The author's choice to divide the anatomical components into three segments has a dual purpose: the first is to have a better quality of the milling and the second is to reduce the material waste of the zirconia disc as much as possible.

Photo 10: The three segments after sintering.

Once the frameworks are obtained, before they are merged with each other, the anatomical parts are finished and polished; only the areas excluded from the functional part will be sandblasted. Special attention must be paid to the surface texturing of the anterior sectors⁵, with cutters, discs and rubbers dedicated for this purpose. The surfaces that remain shiny offer a lower abrasion coefficient than the natural tooth⁶; in fact, the abrasiveness depends on the surface smoothing. Polished zirconia has lower abrasion coefficients than lithium disilicate and layered ceramics⁷.

The adhesion between the anatomical and structural zirconia components is achieved by fusion with Noritake Cerabien ZR Low Fusion ceramic.

Photo 11: Anatomical components joined to the structural framework.

Once the adhesion between the zirconia components has been obtained, the first analog phase involves the creation of the gum parts, with dedicated pink gingival masses at a high temperature of 940 C° (CZR™ Tissue Kuraray Noritake Dental Inc.). The author selects three gingival masses with which the keratinized and vascularised parts are reproduced8, peculiar to the natural gingival tissue.

Photo 12: Used CZR™ Tissue porcelain.

Photo 13: Application of CZR™ Tissue porcelain.

Once the pink gingival parts are finalized, the coloring of the anatomical components will follow with the use of dedicated low temperature stains (CZR™ FC Paste Stain, Kuraray Noritake Dental Inc.) which, together with the high translucency of the anatomical zirconia, guarantees a high aesthetic result.

With gray, blue and black shades, it is possible to give a high degree of translucency to the incisal edges. With warm shades, like orange and yellow, the transitions of the anatomical crowns are emphasized, while with a few spots of strong color it is possible to give character and uniqueness to the teeth.

Photo 14: Used shades of CZR™ FC Paste Stain.

The low baking temperature of CZR™ FC Paste Stain guarantees the non-alteration of the gingival component. The final step involves glazing the sandblasted parts.

Photo 15: Final situation.

Photo 16: Occlusal view.

CONCLUSION

The strength of dento-skeletal rehabilitations made of monolithic zirconia, which is a stable, reliable and highly biocompatible material is, through the possibility of using CAD/CAM technology to make an exact copy of a case or, even better, a functionalized temporary implant.

Photo 17: Matching with wax-up.

The 1125 MPa zirconia is ideal for this type of prosthesis, however, does not offer an aesthetic quality. Therefore, the combination of two zirconia materials, one extremely strong and the other highly aesthetic, fully satisfies this requirement.

Photo 18, 19: Intra-oral situation.

BIBLIOGRAPHY:

1) Matteo Chiapasco, Eugenio Romeo La riabilitazione implantoprotesica nei casi compless, UTET S.p.A. 2003 Unione Tipografico-Editrice Torinese.

2) Piconi C. ,Rimondini L. ,Cerroni L. , La zirconia in odontoiatria, Masson, 2008.

3) Stawarczyk B., Ozcan M., Hallmann L., Ender A., Mehl A., Hammerle CH., Effect of zirconia sintering temperature on flexural strengh, grain size and contrast ratio. Clin oral investig, 2013.

5) Shigeo Kataoka, Yoshimi Nishimura , Morfologia naturale dei denti, Edizione internazionale Milano 2003
La riabilitazione implantoprotesica nei casi compless.

6) Oh W., Delong R., Anusavice K., Factors affecting enamel and ceramic wear: A literature review. J Prosthet Dent 2002.

7) Preis V., Bher M., Kolbeck C., Hahnel S., Handel G., Rosentritt M., Wear performance of substructure ceramics and veneering porcelains, Dent Mater, 2011.

8) Rutten L. & P., L’estetica su impianti, editrice MEA, 1999.

Thanks: Dr. Fortunato Alfonsi, Odt. Raoul Pietropaolo.

Users of dental zirconia are really spoilt for choice these days. Countless manufacturers offer zirconia materials that differ in their mechanical and optical properties and indication range. What is not apparent at first sight is that the available products also differ with respect to the quality of the CAD/CAM blanks offered. Blank quality is highly dependent on the quality of the raw materials and is affected by different aspects during raw material processing, pressing and pre-sintering. This has a huge impact on the surface quality, edge stability, fit and processing requirements of milled restorations.

Raw material production

Pre-shaded dental zirconia typically consists of metal oxides, including zirconium oxide, yttrium oxide and aluminium oxide, as well as additives like binders and colour pigments or ions. Most manufacturers of dental zirconia obtain pre-fabricated powder from an external industry partner, the most popular option being Tosoh Corporation. In contrast, Kuraray Noritake Dental relies on an end-to-end in-house process. This includes the production and addition of the components forming the company’s innovative multilayered technology, which makes it possible to match the shades in the polychromatic blanks precisely to the colours of the VITA classical A1-D4 shade guide.

At Kuraray Noritake Dental, the powder is produced in-house.

Since more powder production steps are carried out in-house, this gives the company full control of the quality of the raw materials, their grain size and the purity of the formulation. It also allows for a precise alignment of the mechanical and optical product properties. Properties of zirconia restorations that are affected by the powder quality and composition include translucency and shade appearance, flexural strength, ageing behaviour and sintering performance.

Blank pressing

Zirconia discs and blocks used for CAD/CAM processing are usually produced by uniaxial and isostatic pressing. In the uniaxial compaction process, pressure is applied to the powder from one direction (uniaxial) or two directions (biaxial), whereas the isostatic compaction process involves virtually equal pressure applied from all sides. Hence, isostatic pressing typically results in a more uniform density distribution throughout the blank and a higher material homogeneity. These factors are prerequisites for a predictable processing and sintering behaviour and affect the fit of the final restoration. For optimal mechanical and optical properties of the zirconia material, it is essential to avoid large porosities, air pockets and impurities caused by airborne particles that are trapped during pressing.

At Kuraray Noritake Dental, a unique and extremely meticulous pressing process achieves a uniform pressure distribution and low risk of contamination by airborne particles. This specific procedure reduces gravitation forces and contributes to having as high as possible density of zirconia material. All the high-level preparation processes from raw material production to pressing are responsible for the high edge stability and surface quality of restorations milled from KATANA™ Zirconia.”

Pre-sintering

The pre-sintering procedure is necessary in that it gives the pressed blanks the required stability to be machinable with milling tools. The selected temperature profile and duration of the pre-sintering cycle determine the material’s strength and processing properties and have an impact on the final sintering process.

The unique pre-sintering procedure carried out in the production facilities of Kuraray Noritake Dental results in blanks that are stable in their pre-sintered state. Although more stable, pre-sintered KATANA™ Zirconia is machinable with common diamond-coated milling tools without any increased risk of breakage or higher tool wear.

A KATANA™ Zirconia blank ready for milling.

Fast sintering for the laboratory

The unique procedure has a positive impact on the surface smoothness after milling and can significantly shorten sintering times. In fact, the speed sintering program offered for all variants of KATANA™ Zirconia is the fastest one on the market. In the dental laboratory, the sintering times may be reduced to 90 minutes^*for single-tooth restorations and bridges of up to three units.

^*The material is removed from the furnace at 800°C.

Overview of the recommended sintering protocols.

Fast sintering for chairside

Using the KATANA™ Zirconia block with Dentsply Sirona’s CEREC system, it is possible to sinter single crowns up to three-unit bridges in 18-30 minutes without compromising the mechanical or optical properties.

The KATANA™ Zirconia block displays superior optical properties after 18 minutes of sintering compared with representatives of major competitors’ raw material after 30-minute and 60-minute sintering programs designed by Kuraray Noritake Dental based on the manufacturer's recommendations.

Unique KATANA™ Zirconia properties

Together, these efforts taken by Kuraray Noritake Dental to produce dental zirconia of exceptionally high quality make all the difference. The KATANA™ Zirconia series - KATANA™ Zirconia Ultra Translucent Multi Layered (UTML), Super Translucent Multi Layered (STML), High Translucent Multi Layered (HTML) and KATANA™ Zirconia High Translucent Mono Layered (HT) - have a homogeneous, high-density structure with low porosity and a high level of purity. This optimises the performance of the blanks during machining.

Surface roughness

SEM image, magnification 33X, of competitor material surface roughness. Image courtesy of Dr Kunkela, Kunkela Research Academy.

SEM image, magnification 33X, of KATANA Zirconia surface roughness. Image courtesy of Dr Kunkela, Kunkela Research Academy.

SEM images of non-polished KATANA™ Zirconia and a competitor’s material at 33x magnification. The four images of each material show the surface structure at different areas of a molar crown. In all areas, the surface of the restoration made of the competitor’s material is rougher and shows more porosity than the surface of the KATANA™ Zirconia crown directly after milling, according to Dr Josef Kunkela’s research results. One of the contributing factors to this result is the more densely pressed blanks with smaller grain sizes of KATANA™ Zirconia.

An optimised processing behaviour leads to regular restoration margins, smooth surfaces and a precise fit of the restorations. The latter is due to the fact that the milling behaviour and volumetric shrinkage during final sintering are highly predictable, so that a user designing a 20 µm cement gap will get what he or she desires. Owing to the great control over optical properties and precise match to the VITA classical A1-D4 shades, KATANA™ Zirconia is considered to be one of the most aesthetic dental zirconia options available on the market.

Excellent marginal fit

SEM images revealing the fit of restorations made of two different materials (lithium disilicate and KATANA™ Zirconia Block STML) on a tooth abutment. The KATANA™ Zirconia restoration shows a more regular margin and more precise fit (with a cement gap of 19-21 µm) than the lithium disilicate crown (cement gap 26-45 µm). Images courtesy of Dr Kunkela, Kunkela Research Academy.

Extremely regular margins of a KATANA™ Zirconia crown after milling, which is also a result of the favourable material structure.

In order to ensure all the desired material properties, including aesthetics and strength, one thing is essential: the machining carried out in the dental laboratory - milling and sintering - needs to adhere to the recommended protocols. This means that the milling machine and furnace should be cleaned and calibrated on a regular basis, which provides the conditions for optimised zirconia processing from the powder to the final, true-to-life dental restoration.

By Dr Alessandro Devigus

Fig. 1. Initial situation with fractured PFM crown.

Fig. 2. Initial situation with fractured PFM crown – problem of deep bite.

Fig. 3. Situation after removal of old crowns and placement of retraction cord.

Fig. 4. Milled crowns before sintering with Speedfire.

Fig. 5. Crowns after sintering.

Fig. 6. Try-in of sintered crowns.

Fig. 7. Crowns after glaze and stain.

Fig. 8. Try-in of finished crowns.

Fig. 9. Crowns after adhesive cementation with PANAVIA™ V5 A2.

FINAL SITUATION

Dentist:

DR. ALESSANDRO DEVIGUS

Dr. Alessandro Devigus received his degree from Zurich University, Switzerland, in 1987. Since 1990 his working in his own private practice with a focus on CAD CAM and Digital Dentistry. He is also CEREC Instructor at the Zurich Dental School.

Dr. Alessandro Devigus is an active member of the European Academy of Esthetic Dentistry (EAED), founder of the Swiss Society of Computerized Dentistry, Neue Gruppe member, ITI fellow and speaker.

Dr. Devigus is editor-in-chief of the International Journal of Esthetic Dentistry, author of various publications and an international lecturer.

By Dr Luca Dusi

For purely aesthetic reasons, this patient asked for the reconstruction of her cone-shaped upper right lateral incisor (12). The patient was offered a treatment including a first phase of orthodontic therapy aimed at recovering the space necessary to be able to reconstruct the lateral incisor to its ideal size. As the patient refused to undergo this orthodontic therapy, it was decided to restore the tooth with resin composite and match its size to the space already available.

The adhesive system used was CLEARFIL™ SE BOND 2, while the restoration was created with the new composite CLEARFIL MAJESTY™ ES-2 Universal. Although this material is designed for the single-shade technique with only two shades matching the anterior tooth shades, I decided to combine both pastes to achieve the best possible outcome. The shade UD (Universal Dark) was used to reconstruct the cervical and central portion of the lateral incisor. The incisal portion was restored with UL (Universal Light).

Fig. 1. Initial situation with a cone-shaped upper right lateral incisor (12).

Fig. 2. Image of the initial situation taken with a polarising filter for shade evaluation purposes.

Fig. 3. The new CLEARFIL MAJESTY™ ES-2 Universal composite with only two shades for the anterior region was chosen. It offers a good optical integration thanks to Kuraray Noritake Dental’s Light Diffusion Technology.

Fig. 4. Shade determination with the aid of cured samples of CLEARFIL MAJESTY™ ES-2 Universal UL (Universal Light) and UD (Universal Dark) on the tooth surfaces.

Fig. 5. Isolation with rubber dam.

Fig. 6. CLEARFIL™ SE BOND 2 used for the establishment of a strong bond between the tooth structure and the composite material.

FINAL SITUATION

Fig. 7. The universal composite blends in well with the adjacent teeth regarding its colour and surface finish.

Dentist:

• Graduated with honors in Dentistry and Dental Prosthetics at the University of Milan in 2010.
• In 2011/2012 and 2012/2013 he held the position of Adjunct Professor for the teaching of Prosthetic Technologies at the University of Milan-Bicocca.
• Member of SIdp (Italian Society of Periodontology) and AIC (Italian Academy of Conservation).

Time has always been limited in dental offices, and COVID-19 sanitisation requirements have constrained this even further. Streamlining procedures is a logical strategy for reducing chair time; however, this optimisation must still ensure a high treatment standard and aesthetic outcome.

The CLEARFIL MAJESTY™ ES-2 Universal shades concept from Kuraray Noritake Dental enables this: fast shade determination and creation of aesthetic, long-lasting direct restorations with a single shade in your regular cases; an opaquer or blocker is no longer needed.

CLEARFIL MAJESTY™ ES-2 Universal shades concept consists of a compact shade range:

• The universal (U) shade is for all posterior restorations.
• For the aesthetically more demanding anterior, the user is given two shade options: universal light (UL) and universal dark (UD).
• The universal white (UW) shade is employed for certain cases, such as the restoration of primary teeth.

This simplified shade concept works so well thanks to the integration of Kuraray Noritake Dental’s light diffusion technology, which makes restoration distort light in a similar way tooth structure does. Consequently, the applied material blends virtually invisibly into the surrounding tooth structure.

Convincing mechanical properties make CLEARFIL MAJESTY™ ES-2 Universal shades very well suited for posterior and anterior restorations alike. Just like other members of the CLEARFIL MAJESTY™ ES-2 family, this innovative product offers high strength, favourable wear and balanced shrinkage stress for reliable performance — even in load-bearing posterior areas. The material is easily polished and retains its gloss, yielding a natural-looking appearance that is particularly beneficial in the anterior region.

The CLEARFIL MAJESTY™ ES-2 Universal shades, available in preloaded-tip capsules and syringes, provide a time-saving and simplified means of realising aesthetic, strong and lasting restorations.

This is streamlining of direct composite procedures in optimum form - in short: intelligent simplification!

Clinical case by Dr Zorzin.

Volume 7 of our "BOND" magazine is now published and ready to read!

Content Highlights:

• Composites versus hybrid ceramics
• Flowable composites a universal solution?
• Universal adhesives, is one bottle sufficient?

Start Reading: BOND | VOLUME 7 | 10/2020

Previous versions:

BOND | VOLUME 6 | 03/2020

BOND | VOLUME 5 | 05/2019

BOND | VOLUME 4 | 06/2018

BOND | VOLUME 3 | 10/2017

BOND | VOLUME 2 | 04/2017

BOND | VOLUME 1 | 12/2016

Dental photography as a valuable documentation aid

The main purpose of photography in dentistry is documentation. The aim is to collect as much information as possible under reproducible conditions. For this purpose, the camera used, its accessories and the format and lighting of the intra- and extra oral recordings relevant to dentistry must be standardized. Under standardized photographic conditions, the recordings made can be compared with one another, even if the later recordings are made only after a long period of time and by different photographers. Only in this form can dental photography be used as a valuable documentation aid. The standards described by Wolfgang Bengel in 1985 are still valid, but they have to be updated and adapted to technical innovations.

In this webinar, the current development in the field of dental photography and related areas will be briefly explained.

Dr. Alessandro Devigus has had his own practice with a focus on CEREC since 1990, editor-in-chief of the International Journal of Esthetic Dentistry.

Topic: Dental photography as a valuable documentation aid
Date: Wednesday. October 14, 2020 - 17:00 - 18:30 CEST
Time: approx. 90 min (including discussion and questions)

ZIRCONIA: NEW INSIGHTS INTO TRIED AND PROVEN MATERIAL

You learn from your mistakes, but it’s better if you can learn from those of others. Dr. Dirawi will share his experience, tips and tricks when it comes to creating perfect Zirconia restorations.
Having great material like KATANA Zirconia is an excellent starting point. Yet to achieve highly aesthetic outcome you need to be aware of the unexpected pitfalls and challenges that can be prevented.
Join our webinar and learn what Dr. Dirawi has to say after years of using Zirconia. Bonus – we will have a conversation about cementation of zirconia as well, to achieve durable robust results.

DR WISSAM DIRAWI DDS, MALMÖ, SWEDEN

• Teacher at Malmö Dental University in Sweden
• Researcher in the fields of ceramics and implant complications
• Long clinical experience from public dental care and private dental care
• Expert in ceramics, implants and digital dentistry
• 2018 - Specialist in Oral Prosthodontics
• 2000 - DDS

Did you know that CERABIEN™ ZR FC Paste Stain has a layer of transparent liquid on top of the liquid ceramic?

This layer protects the material from dust and dirt.

Hence, it is best left in place.

By Daniele Rondoni, RDT

Considering different criteria to select the ideal zirconia and frame design to meet the level of esthetics requested.

Step 1
Final Preparations.

Step 2
Zirconia Frame (KATANA Zirconia STML A2) cut-back designed to reproduce translucent incisal area.

Step 3
Application of 1st Internal Stain and firing.

Step 4
Application of 1st Luster, Clear Cervical and firing.

Step 5
Application of 2nd Internal Stain and firing.

Step 6
Application of 2nd Luster, and Opacious Body.

Step 7
Completion of firing.

Step 8
Completion of morphological correction.

Step 9
Post-operative view.