429 Too Many Requests

Om hun producten te verbeteren en nieuwe producten te introduceren, maken sommige bedrijven voornamelijk gebruik van basistechnologieën die zijn ontwikkeld door anderen; andere ondernemingen voeren fundamenteel onderzoek uit en ontwikkelen technologie in eigen huis. Is dat verschil relevant voor de professionals die de betreffende producten dagelijks gebruiken in tandarts- of tandtechnische praktijken? Dat is inderdaad relevant; bedrijven die alles vanaf het eerste begin ontwikkelen, hebben doorgaans namelijk een diepgaander begrip van de producten en hun productieprocedures. Zij kunnen dan ook gemakkelijker specifieke producteigenschappen aanpassen, bestaande problemen oplossen en inspelen op de behoeften van de markt. In dit artikel wordt ingegaan op de impact die verschillende door Kuraray Noritake Dental Inc. ontwikkelde basistechnologieën hebben op de workflow voor de vervaardiging van directe composietrestauraties.

Directe restauraties - van complex tot eenvoudig

Adhesieve restauratieve tandheelkunde met gebruikmaking van hoogwaardige tandheelkundige adhesieven en harscomposieten is momenteel een van de meest populaire methoden voor de behandeling van cariëslaesies.
Tegenwoordig zijn een single-bottle universeel adhesief plus één of twee kleuren en opaciteiten van een universele composiet meestal voldoende - mits de juiste materialen worden gekozen - om prachtige en duurzame resultaten te realiseren. Dat is echter niet altijd het geval geweest. De ingezette technieken voor de vervaardiging van directe restauraties waren lange tijd behoorlijk complex; de adhesieven bestonden uit technisch gevoelige multibottle- en meerstapssystemen met lange verwerkingstijden. Anderzijds werden met composietvulmaterialen alleen natuurgetrouwe resultaten bereikt als verschillende kleuren en opaciteiten op de juiste manier werden gecombineerd. En zelfs als de complexe procedures correct werden uitgevoerd, was er een relatief hoog risico van microlekkage, verkleuring en - uiteindelijk - secundaire cariës. Kuraray Noritake Dental Inc. heeft zich al in een vroeg stadium geconcentreerd op een oplossing voor deze problemen, te beginnen met de toepassing van het in 1981 ontwikkelde originele MDP-monomeer.

Optimalisatie van de hechtsterkte

Het originele MDP-monomeer loste het probleem op van de beperkte levensduur van de hechtsterkte van adhesieve systemen. De hydrofiele MDP-groep (fosfaat) vormt een uitzonderlijk sterke en duurzame en chemische hechting aan calcium, dat voorkomt in hydroxyapatiet, de basiscomponent van glazuur en dentine. Het gevormde MDP-Ca-zout biedt de basis voor een stabiele, sterke en duurzame hybridelaag. In combinatie met de hars van het hechtmiddel resulteert dit in een solide sealing van de caviteit na lichtuitharding. Tot op de dag van vandaag is MDP een essentiële component van alle adhesieve producten van Kuraray Noritake Dental Inc. en dankzij dit cruciale bestanddeel is CLEARFIL™ SE Bond het zelfetsende adhesieve systeem met de Gouden Standaard geworden.

Kuraray Noritake Dental Inc. was er echter van overtuigd dat tandheelkundige adhesieven méér dienden te bieden dan alleen een sterke en duurzame bevestiging en ging zich daarom richten op de oplossing van een ander probleem: het risico van demineralisatie en cavitatie, veroorzaakt door bacteriën die achterblijven in de caviteit. Op basis van ervaring in de ontwikkeling van andere adhesieve monomeren vond Kuraray Noritake Dental Inc. het MDPB-monomeer uit, met een antibacterieel reinigend effect voor de caviteit. Anders dan antibacteriële producten die de hechtsterkte van een opvolgend adhesief zouden kunnen aantasten, doodt het MDPB-monomeer de achterblijvende bacteriën zonder afbreuk te doen aan de hechtsterkte. Het monomeer is verwerkt in de primer van het two-bottle zelfetsende adhesief CLEARFIL™ SE Protect en wordt via polymerisatie geïmmobiliseerd.

Het bacteriologische mechanisme van MDPB wordt verondersteld gelijk te zijn aan de welbekende antibacteriële agens CPC (CetylPyridiniumChloride), die voorkomt in vele tandpasta‘s en mondspoelproducten.

Hoewel de adhesieve procedure al is vereenvoudigd door two-bottle zelfetsende adhesieven, gaan universele singlebottle adhesieven net nog een stapje verder. Het is een uitdaging om de ingrediënten die worden gedistribueerd binnen multi-stepsystemen samen te brengen in één flacon, zonder afbreuk te doen aan de stabiliteit van het product. Dankzij de huidige technologie is dit nu mogelijk. Om het oppervlak zo snel mogelijk na het aanbrengen te sealen, dienen de monomeren snel en efficiënt door te dringen in het tandweefsel. Die penetratie wordt doorgaans echter vertraagd door monomeren die tijd nodig hebben om door te dringen tot de tandstructuur - in het bijzonder vochtig dentine - en soms zelfs moeten worden ingewreven. Om die reden heeft Kuraray Noritake Dental Inc. zich geconcentreerd op de ontwikkeling van de Rapid Bond Technology. Deze technologie omvat het originele MDP-monomeer dat, in combinatie met nieuw ontwikkelde hydrofiele, gecrosslinkte amidemonomeren, is verwerkt in CLEARFIL™ Universal Bond Quick. De hydrofiele amidemonomeren zorgen voor een snelle, diepe en volledige penetratie in het dentine en vormen na lichtuitharding een dicht gecrosslinkt polymeernetwerk, dat garant staat voor een sterke en duurzame hechting. Zodoende gaat er geen tijd meer verloren met wachten en masseren; na lichtuitharding is de caviteit solide en langdurig geseald.

Vanwege hun hydrofiliciteit (wateraffiniteit) dringen de amidemonomeren van de Rapid Bond Technology goed door in het dentine. Na lichtuitharding heeft de bonding een lage waterabsorptie en daarmee een hoge verouderingsbestendigheid.

Optimalisatie van directe restauraties

Combineren van meerdere lagen, kleuren en opaciteiten; het gebruik van uiterst complexe layeringtechnieken voor de vervaardiging van natuurgetrouwe composietrestauraties behoort in vele klinische situaties gelukkig tot het verleden. Dat is te danken aan hoogwaardige harscomposieten die zich naadloos voegen naar de omliggende tandstructuur. Om deze gunstige producteigenschap te realiseren, heeft Kuraray Noritake Dental Inc. haar Light Diffusion Technology (LDT) ontwikkeld. Deze technologie is verwerkt in speciale geprepolymeriseerde vuldeeltjes die werken als miljoenen microprisma‘s, die licht en kleur van de omliggende tandstructuur overdragen en afbuigen. De vuldeeltjes zijngeoptimaliseerd qua afmeting, verdeling en refractie-index en bieden dan ook een ongeëvenaarde natuurlijke vermenging. Deze propriëtaire vultechnologie is verwerkt in het volledige composietaanbod CLEARFIL MAJESTY™ in het nieuwste product - CLEARFIL MAJESTY™ ES-2 Universal - maakt Kuraray Noritake Dental Inc. gebruik van geavanceerd LDT voor een monochrome techniek met vereenvoudigde kleurselectie; dit product is beschikbaar in twee kleuren voor het anterieure gebied en één kleur voor het posterieure gebied. Het harmonieert echter zo fraai dat vrijwel alle kleuren van de klassieke VITA A1-D4 kleurenkaart worden afgedekt.

Juiste refractie en transmissie van licht voor een geweldige optische integratie; de lichtdiffusievuldeeltjes van CLEARFIL MAJESTY™ ES-2 van Kuraray Noritake Dental Inc.

Een fantastische optische uitstraling hangt niet alleen samen met optische integratie en onzichtbare restauratieranden. Daarom heeft Kuraray Noritake Dental Inc. ook vuldeeltjes ontwikkeld die voor de rest zorgen: een natuurlijke oppervlakglans en langdurig behoud van glans. De oplossing die is verwerkt in CLEARFIL MAJESTY™ ES Flow met drie niveaus van vloeibaarheid, is genaamd Submicron Filler Technology en bestaat uit glanzende vuldeeltjes van submicronformaat. Deze vuldeeltjes zijn zo nietig dat lichtreflectie - zelfs na slijtage - een natuurlijk effect oplevert. De uitzonderlijke silaantechnologie van Kuraray Noritake Dental Inc. wordt gebruikt om miljoenen van die submicronvuldeeltjes bij elkaar te brengen en - door de tijd heen - te houden. Daardoor is de lading met vuldeeltjes in de laagviscose composieten hoger en wordt de wateropname beperkt die de kwaliteit van de uitgeharde composiet anders zou aantasten. De perfecte balans tussen de glanzende submicronvuldeeltjes, lichtdiffusievuldeeltjes, harsmatrix en propriëtaire silaantechnologie is verantwoordelijk voor een uitgebalanceerde combinatie van mechanische en optische eigenschappen.

Voorbeeld van een eenkleurige restauratie, vervaardigd van CLEARFIL MAJESTY™ ES-2 Universal.

Conclusie

Adhesieve monomeren en vuldeeltjes- en silaantechnologie staan garant voor een solide combinatie van vuldeeltjes, clusters en harsmatrix; Kuraray Noritake Dental Inc. is overduidelijk een erkende expert op het gebied van adhesieve restauraties. De propriëtaire technologieën die in de afgelopen decennia zijn ontwikkeld, hebben absoluut bijgedragen aan betere prestaties (op lange termijn) van directe restauraties, en aan een gemakkelijker weg naar betrouwbare en esthetische resultaten.

Interview with Andreas Chatzimpatzakis

Fewer bakes, fewer ceramic powders - there is clearly a trend toward simplification in the production of zirconia-based prosthetic work. This is also true for implant-based restorations, which often involve gum parts. DT Andreas Chatzimpatzakis, international trainer for Kuraray Noritake Dental Inc., and the owner of ACH Dental Laboratory in Athens, Greece, shares his approach to high aesthetics in implant prosthodontics in the following conversation.

You are a user of the CERABIEN™ ZR portfolio from the outset. When did you test the products for the first time and why?

Well, it was many years ago when I finished my very first zirconia-based restoration. The reason to test CERABIEN™ ZR was that when I asked the dental technician who had milled the framework which porcelain system to use. He suggested to use CERABIEN™ ZR, which I did. I was immediately impressed by the system and by the outcome I was able to achieve on the first attempt.

Did you ever test any other porcelain systems for ceramic layering?

Yes. Before I becoming an international trainer for Kuraray Noritake Dental Inc., I had the opportunity to test many other porcelain systems for layering on zirconia. Based on this experience, I can say that CERABIEN™ ZR is unique and the best system I have ever used. The reason is that its translucency and chroma are extremely close to natural teeth. In addition, due to a controlled firing shrinkage, a One-Bake Technique may be employed even in long-span restorations.

Your hands-on demonstration at the Kuraray Noritake Dental booth during the IDS 2023 in Cologne focused on White and Pink Aesthetics achieved with CERABIEN™ ZR. Is there a specific concept you use?

Nowadays, everyone producing dental restorations – no matter whether based on natural teeth or on implants – is confronted with increasing aesthetic demands of patients and dental practitioners. The high demands are developed because life-like restorations and cosmetic dental treatment outcomes are presented everywhere in the web and on social media. The showcased quality of outcomes is simply expected, even if the financial budget is limited. To be able to fulfil these demands in the field of implant-based prosthodontics, I have developed an approach that allows me to achieve high aesthetics with little effort. My concept is based on using not too many ceramic powders. For extra chroma and special characterization, I rely on the power of the internal live stain technique, first introduced by Hitoshi Aoshima-sensei.

Please summarize the most important details of your presentation.

The first important detail is the design and characterization of the framework. Before sintering, I apply Esthetic Colorant for KATANA™ Zirconia. After the sintering process, shade base stain and internal stains are mixed and applied. In this way, I create a nice canvas that helps me to achieve a life-like result with only a few selected ceramic powders. In most cases, three to five powders are enough to produce a great result. Among the powders used most frequently are Opacious Body, Body, LTX, Mamelon and CCV. After the first bake and a little grinding, I make use of internal stains again. They offer support in the controlling of the chroma and the integration of special characteristics. When this step is completed, the final build-up is done with one or two ceramic powders, most of the times LT1 and Enamel or LT0. Pink aesthetics are usually created with Tissue 1, 3 and 5. For the free gingiva, LT Coral is my go-to solution. The major goal is always to obtain maximum quality in a minimum of time. To achieve this, a good knowledge of the materials and of course practicing – on both, porcelain build-up and morphology – are strictly required.

Fig. 1. Complex implant-based restoration: Framework design.

Fig. 2. Esthetic Colorant …

Fig. 3.  … applied prior to the final sintering procedure.

Fig. 4. Appearance after sintering.

Fig. 5. Final outcome.

Are there any concrete tips and tricks you would like to share?

For the characterization of the framework, I mix the internal stains with shade base stain powders; mostly with SS Fluoro. For the first bake, especially when the restoration is large and the amount of ceramic to be applied huge, I reduce the heating rate up to 38 degrees per minute. I also increase the drying process up to 17 or even 20 minutes depending to the restoration. Experience shows that these measures optimize the aesthetic outcomes.

You often mention that it is extraordinarily important to understand the morphology of natural teeth to be able to produce beautiful restorations. Why is this the case?

A successful prosthetic restoration needs to offer proper function and aesthetics. Function means a precise fit, perfect contact points and occlusion, a proper emergence profile and interproximal embrasures for self-cleaning etc. All this is described by the term morphology. Aesthetics, on the other hand, is guided by shape and colour. The effort required to establish a proper morphology is much higher (about 70 percent of the total work) than the effort involved in obtaining the right translucency, opalescence and chroma.

What instruments do you use to imitate the morphology of natural teeth and how do you do it?

I usually make use of the Optimum™ Spring Ceramic Brush Size 8 (MPF Brush Co.), stones and diamond burs for detailed grinding and carving after the final bake. I studied morphology at the Osaka Ceramic Training Centre in Japan with Shigeo Kataoka-sensei. According to him, a key factor in creating a perfect macro and micro morphology lies in the shadows. To be able to take into account the interference of light and shadow during grinding, a light source is placed on one side of the restoration.

How many bakes do you need to produce highly aesthetic restorations?

It depends on the case, although in many situations, I nowadays opt for some kind of micro-layering. Lately, I have used micro-layering a lot with internal stain directly on the zirconia framework. In other cases, I do a quick first bake, then the internal staining, a final bake and glazing. For small or single-unit restorations in the posterior region, a One-Bake Technique is often sufficient. Even a Zero-Bake approach using Esthetic Colorant on a monolithic zirconia restoration may be appropriate here, and it is very convenient. If there is a restoration with high aesthetic demands – these are typically single anterior restorations – the technique I select depends on the shade. In some cases, using only the internal stain technique is enough to reach a high aesthetic level, while in other cases, additional steps need to be taken. To my mind, there is no single technique that fits all cases. As mentioned before, I try to achieve high aesthetics in a minimum of time.

Fig. 6. Clinical example of achieving high aesthetics in a minimum of time: Before …

Fig. 7. … and after crown placement.

Fig. 8. High aesthetics …

Fig. 9. … achieved in a minimum of time.

Did your approach change due to the availability of high-translucency zirconia materials with colour (and flexural strength) gradation?

Well, yes! My overall approach changed more to micro-layering. Several years ago, we needed to consider how to mask the framework and how to achieve translucency in areas with limited space. The problem was solved for single-unit and small anterior bridge restorations with the availability of KATANA™ Zirconia UTML and STML. With the introduction of KATANA™ Zirconia YML, a high-translucency material became available for long-span or implant-based restorations as well. We have strength and translucency all in one disc. In most of my cases, the framework material replaces the dentin with regard to morphology and shade. Hence, I need to focus on adding the enamel by applying the transparent and translucent powders. The powders of the internal stain technique are used to characterize the framework, and with a micro-layer of porcelain, the goal of creating an aesthetic restoration in the minimum of time is achieved. This is exactly why I am sure that micro-layering is the future.

What drives you to share your knowledge with others?

My passion! I love my work! And I love to see technicians become better and better. Dental technology is an exciting journey, a journey that begins when the first impression arrives in the dental laboratory, and it ends when the final restoration is cemented into the patient’s mouth. And this journey is so exciting because we change lives. We change people’s personalities, we give them back their smile, we give them back their self-respect. Consider that every day, every single moment working on our bench trying to imitate nature… there is nothing more exciting than that!!!

My approach as an instructor is to lead dental technicians to master the art of observing natural teeth. This is the way every individual will understand morphology and shade. You need no special talent to be a very good dental technician. You need to observe! Your eyes see, your mind understands, and your hands will follow.

Alexander (Alek) Aronin is a master dental technician who dedicated himself to the creation of high-end, handmade porcelain restorations. He runs a dental laboratory and morphology school in Spain, and travels the world as a lecturer and teacher.

The greatest source of inspiration in his professional life is the book Collection of Ceramic Works by Hitoshi Aoshima. Through reading it in 1996, he discovered superb outcomes of working with dental ceramics. Moreover, the book’s content made him realize that the creation of handmade porcelain work is a result of special education and manual skills. Those who want to become masters need a lot of commitment and a striving for continuous improvement, which Alek shows in his work and his classes. We talked to him about his philosophy and his enthusiasm for the creation of lifelike restorations. He shared with us his perspective on the future of dental technology and gave some practical tips on how to achieve a high level of professional satisfaction.

Photo courtesy of Dennis Debiase

Alek, many dental technicians decide to focus on CAD/CAM technology and automated processing of dental ceramics. Due to improvements on the material side, a handmade porcelain layer is no longer necessary in many clinical cases. In this context, the manual refinement process is reduced to a minimum. Why did you decide to take a completely different path and focus on fully manual dental craftsmanship?

The shift towards automated processing is not a matter of choice for dental technicians rather, it is a natural response to the evolution of technology. The high-end manual refinement process remains unchanged. The human element, from communication to hand crafting among skilled individuals and demanding clients, has been a constant so far throughout history. This traditional connection remains stable for centuries.

Digitalisation is not the revolution in the dental industry, and I do not see the benefit of it in our narrow specialization yet. In the area we are working, we do all steps of our case faster, incomparably more precise and more profitable. But we are keeping eye on machines and waiting for a suitable one.

Machines and automated processes widely serve mass production businesses focused on fast, affordable and uniform results in a highly competitive field. Our goal and workflow are different - we provide individual work and personal attention to each of our partners and patients.

So, we do not compete with the production labs and do not interrupt each other, we coexist in parallel worlds as always. A small number of dentists and their patients will always demand personal attention and valued restorations and service of the highest quality.

Many dental technicians admire your work. Yet, you continue to strive for improvement. Why is this the case?

On one side, we are limited by static ceramic material used to mimic dynamic natural teeth that keep changing for a lifetime. On the other side, we are limited by our manual skills. I am still far away from my teachers and Japanese colleagues. My target is to improve the fabrication process. My goal is to achieve the simplicity and imperfectness like Aoshima-sensei.

Alek lecturing at the IDS 2023 in Cologne.
Photo courtesy of Dennis Debiase

We are enjoying the outcome, but prefer to focusing on the improvement of the process, and move on to create a better one. This is what I am learning in Japan, and this is what I teach my students.

Talking about learning: What are the most important aspects a dental technician who wants to improve his skills should have in mind when looking for a good teacher?

Manual skills are very important, but not the only aspect that should be taken into account. Every individual should be motivated and guided and this is a teacher’s job.

I love the traditional Japanese way of teaching and learning: The teachers are passionate, leading the way by evoking emotions and manual skills to bring the best out of every single student. My personal advice for dental technicians who want to become masters in the creation of lifelike high-end dental restorations is to select their teachers carefully and go to a private school or courses whenever they have the chance.

What are the most important tools a dental technician needs to use when trying to create high-end lifelike restorations?

I suggest to focus on four aspects:

1. Documentary dental photography - required for documentation and communication with the dental office and patients using constant (once set and never changed) parameters of the photo equipment.
2. Focus to the biomimetic additive dentistry. This is a minimum machine invasive field. Dental technicians and dentists should be able to develop a deep knowledge about clinical and lab-side procedures to be able communicate with each other.
3. Mastering morphology and function (shape carving), and anatomy (internal staining), which comes with value control and mimicking fine tooth details for best integration in the mouth.
4. Written communication (stop phone calls) is very important, this is the way how to exchange the information between the patient, clinic and lab by strict protocols.

I teach these complex skills in my morphology school and in many of my trainings worldwide. Focusing on the four aspects, a dental technician has a great chance to become a good specialist in a relatively short period of time in a narrow field.

Is material selection important for achieving great results?

I’ve been using Noritake ceramic for most of my life, and the reason is simple: Noritake created their EX-3 porcelain over 40 years ago, and it was so well-made that it has not needed any changes since.

This is showing their consistently high quality and creates unbroken succession in the valuable tradition of passing on techniques and knowledge.

Today, among different generations of dental technicians, we can use and share the same methods, vocabulary and abbreviations, powders, and temperature charts developed by our skilled teachers 30 to 40 years ago. This unique feature sets Noritake and Creation porcelains apart from all other brands and systems in the world.

The other Noritake porcelain I use quite frequently is CERABIEN™ ZR, which is also well-tried and tested and has even some more advantages than EX3.

Is there any final advice you would like to give?

To become a good professional, I suggest to developing in four parallel directions:

1. Practicing on phantoms - fabricating cases and ceramic samples. It helps to experiment and practice with varied materials and techniques.
2. Implementing the achieved techniques in clinical cases.
3. Working with case presentation PowerPoint or Keynote: documenting the working steps in pictures and videos from beginning to end.
4. Mastering the communication using e-mails. Constantly calibrate and adjust the information exchange process between the clinic and lab. Acquire deeper knowledge about the work of each other.

Good luck!

Er zijn bedrijven die voornamelijk gebruikmaken van basistechnologieën die door anderen zijn ontwikkeld om hun producten te verbeteren en nieuwe producten te introduceren, terwijl andere bedrijven fundamenteel onderzoek doen en zelf technologieën ontwikkelen. Is dat verschil relevant voor de professionals die de betreffende producten dagelijks gebruiken in tandarts- of tandtechnische praktijken? Zeker wel. Bedrijven die een diepgaande kennis hebben van de onderliggende componenten, chemie en technologieën kunnen bestaande problemen effectief oplossen en snel en flexibel reageren op de behoeften van de markt. In dit artikel wordt ingegaan op de impact die verschillende, door Kuraray Noritake Dental Inc. ontwikkelde, basistechnologieën hebben op het cementeren van indirecte restauraties

Adhesief cementeren, vroeger en nu

Het gebruik van diverse soorten keramiek voor het frezen van tandheelkundige restauraties opent nieuwe mogelijkheden in de tandprothetiek, waardoor het nu gemakkelijker is om hoogesthetische restauraties te creëren en te plaatsen. Wat vaak onderschat wordt in deze context, is de rol van adhesieve cementeersystemen; deze ondersteunen niet alleen de esthetische uitstraling van de translucente, restauraties, maar bieden ook mogelijkheden voor minder invasieve preparaties en restauratieontwerpen. De eerste systemen die zorgden voor de chemische hechting tussen de elementen en indirecte restauraties, vertoonden verminderde prestaties op de lange termijn en met een hoge gevoeligheid voor techniek. Bovendien was de procedure uitzonderlijk complex. De technologische ontwikkeling bij Kuraray Noritake Dental Inc. leverde een belangrijke bijdrage aan een verbeterde hechtprestatie op lange termijn, terwijl de verwerking ook eenvoudiger werd.

Optimalisering van de hechtsterkte op lange termijn

Om een duurzame hechting van de eerste cementeersystemen aan tandstructuren (vooral dentine) te realiseren, besloot, Kuraray, de moederbedrijf van Kuraray Noritake Dental Inc., in de jaren zeventig zich te richten op de ontwikkeling van een sterker adhesief monomeer. Als eerste stap op weg naar succes introduceerde het bedrijf in 1976 het fosfaatmonomeer Phenyl-P. Vijf jaar later leidden voortdurende inspanningen om de moleculaire structuur te verbeteren en te verfijnen tot de lancering van het populaire MDP-monomeer, dat zorgt voor een bijzonder sterke en duurzame hechting aan glazuur, dentine, metaal en zirkonium.

Het inventiviteit van deze uitvinding wordt benadrukt doordat het nog steeds een essentieel onderdeel is van elk adhesief product en adhesief cementeersysteem van Kuraray Noritake Dental Inc., en inmiddels ook wordt gebruikt door andere fabrikanten om de sterkte en duurzaamheid van hun bevestigingen te optimaliseren. In vergelijking met elders gesynthetiseerd MDP, onderscheidt het Originele MDP-monomer van Kuraray Noritake Dental Inc. zich door een ongeëvenaard niveau van zuiverheid. Onafhankelijke onderzoeken tonen aan dat dit niveau van zuiverheid een positief effect heeft op de hechtingseigenschappen*. Het MDP-monomeer biedt stabiliteit binnen een vochtige omgeving en draagt zo bij aan meer consistente prestaties van het product waarin het is verwerkt.

Het niveau van zuiverheid en de hechtsterkte verschillen per MDP-monomeer.

Er werden drie experimentele zelfetsende primers geprepareerd, die bestonden uit 15 wt.% 10-MDP en afkomstig waren uit verschillende bronnen: KN (Kuraray Noritake Dental), PCM (Duitsland) of DMI (Designer molecules Inc., VS). Met dank aan Dr. Kumiko Yoshihara voor de gegevens.

Voor adhesieve cementsystemen die moeten zorgen voor een sterke hechting met een uitstekende marginale afdichting is het niet voldoende als ze simpelweg een adhesieve monomeer bevatten. Een efficiënte uitharding van dat monomeer is ook een vereiste en die laat zich niet altijd gemakkelijk realiseren. Om te zorgen voor een effectieve uitharding, zowel chemische als onder licht, van PANAVIA™ V5, heeft Kuraray Noritake Dental Inc. de Touch-Cure Technology ontwikkeld. De kern van deze technologie is een nieuw ontwikkelde, zeer actieve polymerisatieversneller in de PANAVIA™ V5 Tooth Primer. Deze werkt samen met het acidische MDP-monomeer en bevordert de polymerisatie vanaf de interface tussen element en cement zodra PANAVIA™ V5 Paste wordt aangebracht op het al geprimede tandoppervlak. In PANAVIA™ Veneer LC - een lichtuithardend cementsysteem met dezelfde primers worden gebruikt - werkt de polymerisatieversneller van PANAVIA™ V5 Tooth Primer volgens hetzelfde mechanisme. Deze draagt bij aan de uitharding van de adhesieve interface; PANAVIA™ Veneer LC Paste biedt een uitstekende stabiliteit in omgevingslicht en wordt door lichtuitharding gepolymeriseerd.

Bijvoorbeeld, dit verschijnsel werd geëvalueerd voor PANAVIA™ F2.0, de voorganger van PANAVIA™ V5. De uitkomst van de studie was dat de eigenschappen ten aanzien van marginale afdichting van PANAVIA™ F2.0 veel beter waren dan die van andere getoetste cementsystemen**. Deze gedocumenteerde, betrouwbare afdichting van de interface komt marginale lekkage minder voor en wordt een hoge graad van polymerisatie bereikt, zelfs in de zelfuithardende modus (zonder lichtuitharding of bij blokkering van het licht door het restauratieve materiaal); het eindresultaat is dus een bijzonder krachtige hechting.

Een bijkomend voordeel van de integratie van de polymerisatieversneller is dat deze functioneert als een sterke reductor. Het natriumhypochloriet, dat bij endodontische behandelingen vaak wordt gebruikt als irrigatieoplossing, wordt geneutraliseerd; op die manier wordt het negatieve effect op de hechtsterkte van de naderhand aangebrachte cementpasta opgeheven.

Cementeren van glaskeramiek vereenvoudigen

Minder flesjes, minder stappen en gestroomlijnde cementeerprocedures: dat is de reden waarom zelfhechtende composietcementen zijn ontwikkeld en geïntroduceerd in het begin van de jaren 2000. De meeste van die producten hebben echter een beperkt indicatiegebied. Ze presteren goed bij het hechten aan zirkonium, metaal, glazuur en dentine, maar worden niet aanbevolen voor hechten aan glaskeramiek, of hebben in dat geval een extra silaanprimer nodig. PANAVIA™ SA Cement Universal, dat MDP bevat, onderscheidt zicht vanwege een andere gepatenteerde technologie van Kuraray Noritake Dental Inc.: het LCSi-monomeer, Long Carbon-chain Silane Coupling agent. Dit monomeer vormt een sterke chemische hechting aan composiet, en glaskeramiek zoals; porselein, lithiumdisilicaat, etc.. Een aparte primer of voorbehandling is niet meer nodig. Dankzij de voordelen van deze technologie onderscheidt PANAVIA™ SA Cement Universal zich duidelijk van andere zelfhechtende composietcementen als een zelfhechtend eenstapscomposietcement, zelfs voor restauraties die van glaskeramiek worden vervaardigd.

De hechtsterkte van dit product aan de tandstructuur kan, indien gewenst, nog worden vergroot door gebruik van het universele adhesief CLEARFIL™ Universal Bond Quick met de Rapid Bond Technology. Deze innovatieve technologie is door Kuraray Noritake Dental Inc. ontwikkeld om problemen - specifiek voor universele adhesieven - op te lossen rondom de trage penetratie in tandstructuren, vooral vochtig dentine. Om een goede penetratie te garanderen, moeten deze adhesieven een lange tijd en actief in de tandstructuur worden gewreven of moeten gebruikers even wachten voordat de laag kan worden uitgehard met licht. De Rapid Bond Technology, samengesteld uit het originele MDP-monomeer en de hydrofiele amidemonomeren, zorgt voor een hoge wateraffiniteit, die leidt tot een snelle en diepe penetratie van vochtig dentine. Dankzij deze technologie kan er bij CLEARFIL™ Universal Bond Quick direct na aanbrengen worden verder gewerkt, zonder negatieve invloed op de hechtsterkte.

Tandheelkundige transformatie dankzij baanbrekende technologieën 

De door Kuraray Noritake Dental Inc. ontwikkelde technologieën hebben een grote bijdrage geleverd aan de verbeterde hechtkracht van adhesieve cementeersystemen en aan een werkelijk universeel gebruik van zelfhechtende composietcementen. Het bedrijf biedt dan ook een gestroomlijnde portfolio van hoogwaardige composietcementen voor elke gebruiker en voor verschillende klinische situaties. Er zijn minder componenten en minder stappen nodig en de procedures zijn vereenvoudigd; dus: minder fouten en duurzame restauraties. De genoemde producten bieden, nog afgezien van de technologiegerelateerde pluspunten, veel bijkomende productvoordelen. Meer informatie via kuraraynoritake.eu.   

Referenties

*) Functional monomer impurity affects adhesive performance.; Yoshihara K, Nagaoka N, Okihara T, Kuroboshi M, Hayakawa S, Maruo Y, Nishigawa G, De Munck J,
Yoshida Y, Van Meerbeek B. Dent Mater. 2015 Dec;31(12):1493-501.
**) Touch-Cure Polymerization at the Composite Cement-Dentin Interface.; Yoshihara K, Nagaoka N, Benino Y, Nakamura A, Hara T, Maruo Y, Yoshida Y, Van Meerbeek
B.J Dent Res. 2021 Aug;100(9):935-94

Interview with Mitsunobu Kawashima
Manager, Technology Division of Kuraray Noritake Dental Inc.

In 1983 – exactly 40 years ago – PANAVIA™ EX was introduced in Japan as the first product of the PANAVIA™ family and the first product containing the original MDP monomer. Since then, the PANAVIA™ family of resin cements has been continuously expanded by developing new resin-cement materials that are precisely adjusted to the contemporary demands of dental practitioners. The current line-up of easy-to-use, high-performance adhesive luting materials is globally available and used by dental practitioners with high quality standards.

We had a conversation with Mr. Mitsunobu Kawashima about PANAVIA™ EX as a ground-breaking innovation in the field of dental resin cements and subsequent steps toward the current well-balanced resin cement portfolio. He is currently responsible for the development of chair-side materials in the Technology Division of Kuraray Noritake Dental Inc. (Kuraray Noritake Dental) and has been part of the team developing the many products of the PANAVIA™ family for more than 30 years.

The resin cements developed by the company before the introduction of PANAVIA™ EX contained the adhesive monomer Phenyl-P. Why did you decide not to use Phenyl-P in the new formulation?

At the time we decided to develop PANAVIA™ EX, we were engaged in the development of new adhesive monomers to replace Phenyl-P. The main aim of this project was an improvement of our products’ bond strength to metal alloys and dentin. Among the new adhesive monomers being developed, we decided to use the MDP monomer, because it features excellent bonding to tooth structure and metal alloys used in dentistry, as well as superb resistance to water. Incidentally, our first products to contain the original MDP monomer were the resin cement PANAVIA™ EX and the bonding agent CLEARFIL™ NEW BOND.

Where did the name PANAVIA™ come from?

The name “PANAVIA™” is a compound word consisting of “PAN” and “VIA”. The former is of Greek origin, and the latter is of Latin origin. “PAN” means “everything” and “VIA” means “way” or “method”. Consequently, the name “PANAVIA” describes a “method for bonding everything”; it represents our desire to have products launched under the umbrella of the PANAVIA™ brand recognized as dental materials that can bond to all types of restoration and tooth structure.

Would you please tell us the story behind the development of PANAVIA™ EX?

Back in the early 1980s, it was indispensable for us to develop new adhesive monomers as a part of our project to develop a new resin cement with unprecedented adhesive properties. In this context, we conducted a comprehensive literature search for compounds thought to be involved in adhesion. At the same time, we carried out a variety of R&D activities, including basic research to quantitatively clarify the relationship between the molecular structures of monomers and their adhesive qualities, synthesis trials of various monomers and bond strength tests. Consequently, we succeeded in developing the MDP monomer that had the physical properties we were working to obtain. Following the development of that MDP adhesive monomer, we were finally able to create PANAVIA™ EX in our laboratory. In early 1982, we completed the first prototype of PANAVIA™ EX for external evaluation and asked a dental college in Japan to evaluate it. He found that the prototype cement might cure too quickly in clinical use. This was due to the fact that we had not taken into account the difference between room temperature and intraoral temperature, which has a huge impact on the curing time. This error led us to recognize how important clinical evaluations are during the development of dental materials. To this day, we continue to place great importance on the opinions of clinicians whenever a new material is being developed.

The name “PANAVIA™” is a compound word consisting of “PAN” and “VIA”. The former is of Greek origin, and the latter is of Latin origin. “PAN” means “everything” and “VIA” means “way” or “method”.

What were the key technological features of this new PANAVIA™ EX cementation system?

The system had five key features: Appropriate film thickness, appropriate flow properties of the paste, radiopacity, improved bond strength and improved surface-cure characteristics. At the time that PANAVIA™ EX was developed, a film thickness of 30 μm or less was desired for luting cements. The largest components we wanted to use in the formulation – the silica filler particles present in our composite resin – had a maximum particle diameter of 50 μm. We were able to achieve a film thickness of 30 μm or less by significantly extending the silica grinding time, which made the filler particles much finer. An appropriate paste consistency – a low level of viscosity and good flowability – was achieved by using low-viscosity monomers for PANAVIA™ EX. In order to make the cement radiopaque, we dispersed radiopaque filler within the powder component. In fact, we were convinced that it was essential to be able to check for the presence of excess cement under the gingival margins after a restoration was placed. The increase in bond strength was achieved by blending the MDP monomer into the liquid component.

What about the surface-cure characteristics of the cement?

Every dental practitioner knows that the surface of resin cements must be protected from oxygen in the air in order to cure properly. For this purpose, we developed OXYGUARD, a water-soluble gel material. It is applied to the restoration margins to cover the unpolymerized resin cement surface and protect it from exposure to oxygen. In this way, the formation of an oxygen inhibition layer – a layer of uncured resin on the surface that compromises the marginal integrity of the restoration – is prevented and an intact, fully polymerized cement surface can develop. In this way, the use of OXYGUARD has contributed greatly to improving the cure characteristics of cements.

What do today’s PANAVIA™ products and PANAVIA™ EX have in common?

The PANAVIA™ family of products, including PANAVIA™ EX, share the concept of “being a resin cement product that opens new dimensions in dentistry”. PANAVIA™ EX was our first resin cement, and it was conceived as a cement for a new era. It can bond to tooth structure and dental metals very well, thanks to the use of the MDP monomer. This important adhesive monomer is still used today in many of our products. Ever since the launch of PANAVIA™ EX, Kuraray Noritake Dental has continued to take on new challenges and has developed many new products in the growing PANAVIA™ family. These include PANAVIA™ 21, a cement in paste form that has a self-etching primer as an accessory; PANAVIA™ Fluoro Cement, a dual-cure cement paste that releases fluoride; and PANAVIA™ F2.0, which can be used with an LED curing unit. The current portfolio consists of PANAVIA™ V5, which features the substantially improved bonding performance that was achieved after a major review of the basic composition of the series, PANAVIA™ SA Cement Universal, which works as a standalone product without separate primers, and PANAVIA™ Veneer LC, PANAVIA™ family’s latest product. The latter is a light-curing resin cement with the specialized purpose of bonding laminate veneers.

In retrospect, what did the introduction of PANAVIA™ EX mean to Kuraray Noritake Dental?

In the development of new resin cements, it is important to quickly respond to the rapidly changing trends in the market. Whenever new prosthodontic treatment concepts appear – like adhesive bridges as a minimally invasive treatment option replacing a single tooth – or new restorative materials are introduced, such as different types of ceramics – we need to check if our resin cement systems are compatible with the tasks that come with these changes, as well as possibly developing new ones. Following the launch of PANAVIA™ EX, we received a wide range of feedback from experts working at dental clinics and laboratories. We leveraged this feedback in subsequent development projects, always striving to stick close to the clinical setting. After Kuraray Medical Inc. merged with Noritake Dental Supply Co., Limited, this ethos was embedded in the work ethic of all employees of Kuraray Noritake Dental.

Can you give us a brief history of the PANAVIA™ EX journey to the currently available PANAVIA™ family portfolio?

Since the launch of PANAVIA™ EX 40 years ago, six different PANAVIA™ products have been released. Each of them has received high acclaim for their unique features, both in the Japanese resin cement market and abroad. For 40 years, we have been improving PANAVIA™ in response to the demands of the times. We developed a product with increased adhesion when non-retentive preparation designs (adhesive bridges) and smaller bonding surfaces (due to less invasive preparations) became popular. And for users concerned about secondary caries, we developed a material with fluoride-releasing properties. At the same time, we focused strongly on making dental cementation easier by finding ways to make our resin cements bond well to various types of crown-restoration materials, including precious metals and ceramics. During these drives towards improvement, “achieving reliable general luting” has always been at the forefront of our goals. We believe that the successful evolution of the PANAVIA™ brand owes a great deal to our incessant efforts to obtain a high level of bond strength to dentin after chemical polymerisation”.

How did the R&D department evolve over the years?

Initially, our efforts in the development of dental materials had focused on bonding agents and restorative composite resins. PANAVIA™ EX was just one of our new development projects and only a few staff members were assigned to that product. After PANAVIA™ EX was launched in 1983 and it was accepted worldwide, our product line-up of resin cements was expanded considerably. Consequently, we have increased the number of development staff assigned to resin cements and set up a special development team responsible for the self-adhesive resin cement product line that includes PANAVIA™ SA Cement Universal. As a result, the size of the team assigned to resin cements has expanded substantially.

How did production change?

When PANAVIA™ EX was launched in 1983, the product was manufactured exclusively for the Japanese market in a relatively small facility. Today, in order to produce all products of the PANAVIA™ family for the global market, we have automated our production facilities and increased the production equipment and systems dedicated to producing the resin cement paste. To support our product quality, we have also set up a quality control system that assures we turn out safe and high-quality products, drawing on over 40 years of technical knowhow and experience in the production of resin cements.

For 40 years, we have been improving PANAVIA™ in response to the demands of the times.

When did external researchers start showing interest in PANAVIA™?

The development of PANAVIA™ EX was carried out with the active participation of researchers at a dental college in Japan, involving such activities as performing basic adhesion tests and experimenting with clinical applications using adhesive bridges. At that time, resin cements that provided a strong bond to tooth structure or metal alloys were not widely used. I believe that overseas researchers were interested in the development of PANAVIA™ EX at a relatively early stage, for this reason.

What current concept do you have in mind as you continue developing your adhesive cements?

We have two basic central concepts: “Achieving greater bond strength” and “Delivering easier handling characteristics”. I think that the shades of resin cements are also devised in each product in order to get the most of the characteristics of aesthetic restorative materials. At our company, we have embodied “achieving greater bond strength” in PANAVIA™ V5, and “delivering easier handling characteristics” in PANAVIA™ SA Cement Universal. We will continue to explore the development and introduction of various new technological applications, to bring even higher performance products to market.

What do you think is the strength of Kuraray Noritake Dental’s R&D team?

We conduct R&D activities continuously, focusing on the development of luting materials. In our product development department, the same person is often responsible for one product category over long period of time. For example, I have been engaged in the development of PANAVIA™ products for much of my time with the company. The result is that each person in the development department can be said to be an expert in a certain category of products. They leverage the technical knowledge acquired in the past for the development of new products, resulting in entirely new discoveries.

Do you have any ideas about what the future of PANAVIA™ will be?

We will continue to focus on the development of even simpler, easier-to-use resin cements suitable for a wide range of applications – products based on the concept of universality. This should allow users to focus more on the actual treatment than ever before, while of course delivering a strong and durable bond between the tooth structure and the restoration.

MITSUNOBU KAWASHIMA

Eight-time DENTAL ADVISOR Top Product selection provides effective relief for a painful condition

Dentine hypersensitivity is a painful condition that affects millions of people worldwide. It generally occurs when tubules are exposed for any number of reasons, including gingival recession, dental erosion or excessive tooth brushing. It can also be a side effect of professional tooth cleaning, scaling and root planning, tooth whitening, or restorative procedures.

TEETHMATE™ DESENSITIZER, which was honored by DENTAL ADVISOR every year from 2015 to 2022 as a Top Product selection, allows an effective non-invasive approach to the treatment of hypersensitivity when used as directed by dental professionals.

TEETHMATE™ DESENSITIZER is designed to crystalize hydroxyapatite (HAp), a mineral that is naturally found in enamel and dentin, and is the human body’s strongest material. When applied to exposed, mechanically treated, or freshly prepared dentin, the calcium phosphate based mixture blocks the exposed tubules and provides immediate pain relief. During setting, HAp is formed, providing for long-term prevention of hypersensitivity. Further, when used in the context of restorative treatment, TEETHMATE™ DESENSITIZER does not have a negative effect on the bond strength of subsequently utilized dental adhesives or cements.

DENTAL ADVISOR clinical study found TEETHMATE™ DESENSITIZER effective in providing hypersensitivity relief immediately following and for up to six months after application. The study evaluated 27 patients diagnosed with gingival recession-related hypersensitivity, which was diagnosed using thermal testing with cold air. For the initial assessment, patients were asked to evaluate their level and frequency of hypersensitivity per tooth on a five-point scale. They were questioned about their level of sensitivity immediately after TEETHMATE™ DESENSITIZER was applied, according to the instructions for use, and again six months later. At baseline, 91 percent of the patients stated that they had no or only mild, sporadic sensitivity, which was still the case for 85 percent after six months.

This natural, tissue-friendly product is highly biocompatible and is free of gum irritants such as glutaraldehyde or methacrylates. It is indicated for use by dental professionals for all  sensitivity challenges in everyday practice, including prevention of cervical hypersensitivity before/after bleaching, scaling or root planning, and underneath restorations.

The Top Product or Preferred Product Awards conferred by US-based DENTAL ADVISOR were introduced to support potential users in identifying high-quality dental materials and determining which among them are best suited to fulfill their individual requirements. Awards are based on results of its practice-based clinical evaluations and product performance tests, which are conducted shortly after product launch.

Among products honored this year are five from Kuraray Noritake Dental Inc.: CLEARFIL™ SE Protect, CLEARFIL MAJESTY™ ES Flow (Low), and PANAVIA™ SA Cement Universal were selected as Top Products; and CLEARFIL™ Universal Bond Quick and CLEARFIL™ CERAMIC PRIMER PLUS were chosen as Preferred Products.

Article by Dr. Adham Elsayed

High-performance adhesive resin cements are often the enablers of minimally invasive prosthodontic treatments. When the main aim is to save as much healthy tooth structure as possible, preparation designs that offer sufficient macro-mechanical retention for conventional cements are usually abandoned. The designs chosen instead need to rely on a strong and durable chemical adhesion established between the tooth structure and the restorative material – a task successfully accomplished by modern adhesive resin cement systems.

An excellent example of a minimally invasive, non-retentive preparation and restoration design is the single-retainer resin-bonded fixed dental prosthesis (RBFDPs), nowadays usually made of 3Y-TZP zirconia. With its single cantilever bonded to the oral and proximal enamel surface of an adjacent tooth, it requires minimal to no healthy tooth structure removal. The RBFDP is often used to replace a congenitally missing tooth – in many cases a maxillary lateral incisor – in young patients with incomplete dentoalveolar development and narrow edentulous spaces unsuitable for conventional implant placement¹ (Fig. 1 and 2). Additional factors hindering implant therapy – like an insufficient bone volume or angulated roots – are also not an issue for this type of restoration. And compared to orthodontic gap closure, the treatment approach with a RBFDP is less risky, as it does not affect the vertical jaw relationship, prevent canine guidance or compromise the aesthetic appearance². Finally, it is much less invasive than conventional FDPs, which is usually not a treatment option for young patients in the anterior region. The level of patient satisfaction and the success rates of this treatment approach are impressive^3-7.

Fig. 1-2. Replacement of both congenitally missing maxillary lateral incisors with single-retainer zirconia RBFDPs after soft tissue augmentation and gingival margin correction.

Despite the numerous advantages and excellent clinical performance – single-retainer RBFDP made of zirconia showed a survival of 98.2 percent and a success rate of 92.0 percent after ten years⁴ – many dental practitioners still opt for alternative treatment options. The reason may be a lack of trust in the bond strength and durability to zirconia. However, this bond can be very strong and durable – provided that a few rules are respected.

HOW TO ESTABLISH A STRONG BOND TO THE TOOTH STRUCTURE

In order to decide whether a missing tooth may be successfully replaced by a single-retainer RBFDP made of zirconia, the abutment tooth should be examined carefully. It needs to be vital and largely free of caries or direct restorations, while the oral enamel surface must be large enough for resin bonding¹. In addition, the space required for the placement of a retainer wing (thickness: about 0.7 mm) needs to be available, as a non-contact design is important for the success of the restoration. Among the preparation designs described in the literature is a lingual veneer and small proximal box preparation with retentive elements located in the enamel only¹, or no preparation at all⁷. For restoration placement, the abutment tooth is treated as usual: after cleaning e.g., with fluoride-free prophylaxis paste, phosphoric acid etchant is applied to the bonding surface, which is then thoroughly rinsed and dried.

HOW TO ESTABLISH A STRONG BOND TO THE RESTORATION

The recommended pre-treatment for the bonding surface of the retainer wing made of zirconia is small-particle (50 μm) aluminium oxide air-abrasion at a low pressure (approx. 1 bar)^8,9, followed by ultrasonic cleaning. Figures 3 (A-E) shows the sequence of surface treatment of zirconia restorations. As a visual aid for a controlled air-abrasion treatment, the marking of the surface with a pen has proven its worth. The whole air-abrasion procedure should be carried out after try-in, during which the tooth surface and the restoration usually becomes contaminated through contact with saliva and sometimes blood. Proteins present in saliva and blood that contaminate the bonding surface are safely removed in this way, while the required surface modification necessary to establish a strong and durable bond to the selected resin cement system is achieved¹⁰.

FIGURE 3: SEQUENCE OF SURFACE TREATMENT OF ZIRCONIA RESTORATION.

Fig. 3A. Cleaning of the restoration prior to luting with water steam cleaner.

Fig. 3B. Marking of the bonding surface as an visual aid for the air-abrasion.

Fig. 3C. Air-abrasion with 50-μm Al₂O₃ particles with 1 bar pressure.

Fig. 3D. Application of a primer containing 10-MDP.

Fig. 3E. Application of the composite resin cement.

WHICH RESIN CEMENT SYSTEM TO CHOOSE

Subsequently, the components of the resin cement system are applied. Regarding the selection of the system, it is generally recommended to use a restoration primer or resin cement that contains 10-Methacryloyloxydecyl dihydrogen phosphate (10-MDP)¹¹. In this way, a high-quality chemical bond is established. Among the resin cement systems used in the available long-term clinical studies is PANAVIA™ 21 (Kuraray Noritake Dental Inc.)^4-6. Launched in 1993, this anaerobic-curing adhesive resin cement contains several important technologies like the MDP monomer and the Touch Cure Technology found in PANAVIA™ V5, the state-of-the art dual-cure multi-bottle adhesive resin cement system of the company. In order to further improve the bonding performance of this present product, however, the team of developers reviewed the basic composition, updated existing technologies and combined them with completely new ingredients.

Even with PANAVIA™ 21 introduced 30 years ago, high success rates were obtained^4-6. The few observed failures were mainly due to chipping of the veneering ceramic or debonding. Sometimes caused by traumatic incidents, the debondings resulted in no further damage and the restorations were simply rebonded using the same cementation system and procedure.

One might expect that with its improved formulation, PANAVIA™ V5 will offer an even stronger and more durable bond than predecessor products, so that it is even better suited for such demanding applications as the resin-bonded fixed dental prosthesis. In a pilot study, this assumption was confirmed⁷. Without any preparation of the abutment tooth, but a defined size of the bonding surface of at least 35 mm², the team of researchers placed 24 monolithic zirconia resin-bonded bridges (made of KATANA™ Zirconia HT) to replace congenitally missing lateral incisors. The palatal sides of the central incisors were cleaned with pumice paste and treated with phosphoric acid, while the bonding surfaces of the restorations were sandblasted with aluminum oxide particles (50 μm, 2.5 bar pressure). Afterwards, twelve restorations were luted with PANAVIA™ V5, the other twelve with PANAVIA™ F2.0 (another earlier-version resin cement from Kuraray Noritake Dental Inc.). After an observation period of 32 to 50.47 months, the success and survival rates in the PANAVIA™ V5 group were 100 percent. In the other group, a connector fracture, a chipping and two debondings occurred. Based on these results, the authors of the publication concluded that “it has been seen that the new generation cement (PANAVIA™ V5) is more successful”⁷.

CONCLUSION

For many years, minimally invasive indirect restorative approaches like the replacement of missing incisors with resin-bonded fixed dental prostheses have been performed successfully by some dental practitioners. Many others, however, still seem to be hesitant whether these approaches will lead to the desired results in their hands. The available clinical study results, however, have confirmed that the procedure is highly advantageous and successful, while ongoing development efforts in the field of adhesive resin cements have led to products further decreasing the failure rates related to debonding. Even if a debonding occurs, however, no damage is usually done, so that the restoration can be rebonded again with little effort. These findings – together with the well-known benefits of minimally invasive dentistry in general – should encourage dental practitioners to start exploring the full potential of adhesive dentistry for themselves. In this context, PANAVIA™ V5 is definitely an excellent choice.

References

1. Sasse M, Kern M. All-ceramic resin-bonded fixed dental prostheses: treatment planning, clinical procedures, and outcome. Quintessence Int. 2014 Apr;45(4):291-7. doi: 10.3290/j.qi.a31328. PMID: 24570997.
2. Tetsch J, Spilker L, Mohrhardt S, Terheyden H (2020) Implant Therapy for Solitary and Multiple Dental Ageneses. Int J Dent Oral Health 6(6): dx.doi. org/10.16966/2378-7090.332.
3. Wei YR, Wang XD, Zhang Q, Li XX, Blatz MB, Jian YT, Zhao K. Clinical performance of anterior resin-bonded fixed dental prostheses with different framework designs: A systematic review and meta-analysis. J Dent. 2016 Apr;47:1-7. doi: 10.1016/j.jdent.2016.02.003. Epub 2016 Feb 11. PMID: 26875611.
4. Kern M, Passia N, Sasse M, Yazigi C. Ten-year outcome of zirconia ceramic cantilever resin-bonded fixed dental prostheses and the influence of the reasons for missing incisors. J Dent. 2017 Oct;65:51-55. doi: 10.1016/j.jdent.2017.07.003. Epub 2017 Jul 5. PMID: 28688950.
5. Kern M. Fifteen-year survival of anterior all-ceramic cantilever resin-bonded fixed dental prostheses. J Dent. 2017 Jan;56:133-135.
6. Sasse M, Kern M. Survival of anterior cantilevered all-ceramic resin-bonded fixed dental prostheses made from zirconia ceramic. J Dent. 2014 Jun;42(6):660-3. doi: 10.1016/j.jdent.2014.02.021. Epub 2014 Mar 5. PMID: 24613605.
7. Bilir H, Yuzbasioglu E, Sayar G, Kilinc DD, Bag HGG, Özcan M. CAD/CAM single-retainer monolithic zirconia ceramic resin-bonded fixed partial dentures bonded with two different resin cements: Up to 40 months clinical results of a randomized-controlled pilot study. J Esthet Restor Dent. 2022 Oct;34(7):1122-1131. doi: 10.1111/jerd.12945. Epub 2022 Aug 3. PMID: 35920051.
8. Kern M. Bonding to oxide ceramics—laboratory testing versus clinical outcome. Dent Mater. 2015 Jan;31(1):8-14. doi: 10.1016/j.dental.2014.06.007. Epub 2014 Jul 21. PMID: 25059831.
9. Kern M, Beuer F, Frankenberger R, Kohal RJ, Kunzelmann KH, Mehl A, Pospiech P, Reis B. All-ceramics at a glance. An introduction to the indications, material selection, preparation and insertion techniques for all-ceramic restorations. Arbeitsgemeinschaft für Keramik in der Zahnheilkunde. 3rd English edition, January 2017.
10. Comino-Garayoa R, Peláez J, Tobar C, Rodríguez V, Suárez MJ. Adhesion to Zirconia: A Systematic Review of Surface Pretreatments and Resin Cements. Materials (Basel). 2021 May 22;14(11):2751.
11. Al-Bermani ASA, Quigley NP, Ha WN. Do zirconia single-retainer resin-bonded fixed dental prostheses present a viable treatment option for the replacement of missing anterior teeth? A systematic review and meta-analysis. J Prosthet Dent. 2021 Dec 7:S0022-3913(21)00588-6. doi: 10.1016/j.prosdent.2021.10.015. Epub ahead of print. PMID: 34893319.

“Very nice handling properties”

PAVANIA™ Veneer LC SCOORT 4,6 UIT 5 IN DE FIVE STAR AWARD VAN REALITY

Na een in mei 2022 gepubliceerde FirstLook-evaluatie heeft een beoordelingsteam van REALITY RATINGS & REVIEWS binnen een klinische praktijkomgeving PANAVIA™ Veneer LC grondig onder de loep genomen. De resultaten waren geweldig. Aan het puur lichtuithardende composietcement werden 4,6 van de vijf sterren van de Five Star Award toegekend, waarbij de verwerking en viscositeit de meest overtuigende producteigenschappen waren.

De meeste teamleden gebruikten PANAVIA™ Veneer LC voor het permanent cementeren van veneers, maar enkele beoordelaars hebben ook de onlay-indicatie getest (beperkt tot hoogtranslucente materialen met een materiaalspecifieke maximale dikte). Degenen die besloten om de randen te polijsten (43%) stelden vast dat het harscement met een geringe inspanning heel goed is te polijsten. De naar voren gebrachte verwerkingseigenschappen waren onder andere: een gemakkelijke plaatsing zonder noemenswaardig afglijden, het niet-plakkerige karakter en de gemakkelijke verwijdering van overmaat, zowel na tack-curing als in de niet-uitgeharde staat (wet-cleanup) van het cement. Bovendien prezen de beoordelaars de superlage filmdikte en prettige viscositeit, die de plaatsing aanmerkelijk vergemakkelijkt. De verwerkingstijd was voldoende voor alle beoordelaren, ongeacht hun werkwijze (al dan niet filteren/blokkeren van het licht van de operatielamp, gelijktijdige plaatsing van meerdere veneers of steeds één veneer).

Het kleuraanbod - PANAVIA™ Veneer LC is leverbaar in de vier kleuren Clear, Universal/A2, Brown/A4 en White - werd door de meeste beoordelaars (79%) als adequaat ingeschat, waarbij Clear de populairste kleur was. Zoals een van de beoordelaars stelde: 'Ik denk wel dat Clear mijn nieuwe favoriete kleur is. In vergelijking met andere heldere of translucente cementen lijkt deze kleur een zekere helderheid te hebben.' Er werd vastgesteld dat White, de enige kleur met een hoge opaciteit, een doorslaggevende invloed had op de uitstraling van de uiteindelijke restauratie. De try-inpasta's werden goed ontvangen, omdat ze goed konden worden verwerkt en gemakkelijk weggespoeld.

De PANAVIA™ Veneer LC-kit die in Europa wordt geleverd, bestaat uit PANAVIA™ Veneer LC Paste, PANAVIA™ V5 Tooth Primer en CLEARFIL™ CERAMIC PRIMER PLUS. Deze kit biedt dus vertrouwen dankzij de combinatie met een beproefde primer uit het PANAVIA™ V5-assortiment; de lange verwerkingstijd en prettige verwerkingseigenschappen zijn bijkomende voordelen die tijdens het cementeren van veneers bijzonder waardevol zijn. Klik hier om het volledige artikel te lezen!

Article by Dr. Bassem Jaidane

Among the most common problems in modern dentistry is that of restoring a patient‘s lost aesthetic dental appearance. To do this, new technologies are available to practitioners. For anterior teeth where aesthetics are paramount, dentists prefer the least invasive treatments possible, such as layered dental veneers (cut-back). In cosmetic dentistry, practitioners are often faced with cases requiring a multidisciplinary treatment plan or different types of restorative materials to be used at the same time. For cases of prosthetic restoration combining dental veneers, dental crowns and dental bridges, dentists are often faced with situations where the difference in shade is noticeable in the final result, this is explained by the difference in restorative material, product, adhesion technique, the thickness of the prosthetic element and the colour of the abutment, whether it is a living natural tooth, devitalized, or even an implant abutment^1-2.

In the presence of a treatment plan requiring dental veneers, crowns and dental bridges, choosing zirconia as the only restorative material is no longer an option but an obligation. The is due to the limited mechanical properties of lithium disilicate and feldspar porcelain restorations, which contraindicate their use as dental bridges. There are different factors explaining the reluctance of practitioners to use the zirconia dental veneer technique³: One is the absence of the vitreous phase. It makes impossible to create an optimal adhesion surface with hydrofluoric acid at the level of the intaglio of the zirconia veneers. Another is the lack of translucency of the first zirconia generations.

Modern zirconia materials, however, are particularly well-suited for cases requiring a combination of veneers, crowns and dental bridges of the same optical appearance. This is due to their increased translucency and excellent mechanical properties. The following article describes and discusses the realization of a clinical case treated with dental veneers and a crown using KATANA™ Zirconia UTML (Kuraray Noritake Dental Inc.). the veneers were placed with PANAVIA™ Veneer LC (Kuraray Noritake Dental Inc.). The patient presented an aesthetic problem at the level of an anterior implant-supported crown.

CASE OBSERVATION

Patient S, from the Tunisian Sahel, engineer in France, with no significant pathological history and aged 29, presented in January 2023 due to an aesthetic problem negatively affecting her smile. The extraoral examination was without abnormalities, while the intraoral examination showed good oral hygiene, healthy gums, a thin free gingiva and a protruded zirconia crown on an implant in the region of the maxillary right central incisor (figs 1 and 2).

Fig. 1. Initial clinical situation.

Fig. 2. Occlusal view revealing the volume and position of the crown on the central incisor.

During the preliminary interview, it turned out that the implant in the region of the right central incisor had been placed in 2020. The patient’s former dentist had left Tunisian territory. The patient does not have any document or reference on the dental implant, and she wishes to “straighten” the crown and improve the aesthetics of her smile before her planned wedding ten days after her first consultation.

TREATMENT PLAN

After having had the informed consent of the patient and after having asked the indication of dental veneers for aesthetic reasons, the treatment was initiated. According to the treatment plan, seven maxillary anterior teeth (from first premolar to first premolar) should receive an incisal overlap preparation (depth: 0.1 to 0.3 mm) for the placement of veneers made of KATANA™ Zirconia UTML. For the implant in the region of the right central incisor, it was planned to replace the existing crown by a crown made of KATANA™ Zirconia UTML without replacing the abutment. This was due to the lack of information about the implant type and the lack of time.

TREATMENT

After taking the preoperative photos (fig 3), choosing the color of the veneers and anesthetizing the maxillary anterior region, the incisal overlap preparation was carried out on the seven maxillary teeth and the zirconia crown was removed from the implant. A cylindrical diamond bur was used to separate the zirconia part from the abutment. Subsequently, a bite record and impressions were taken using the wash technique. In addition, a temporary crown was produced and placed on the abutment.

Fig. 3. Preoperative picture.

In the dental laboratory, virtual models were created based on the conventional impressions (fig. 4). Then, the zirconia restorations were designed in full contour, cut back for the veneering porcelain and finished by layering with CERABIEN™ ZR porcelain (Kuraray Noritake Dental Inc.). At try-in during the second session, we checked the insertion, the gingival margins, and the contact points between the veneers and the crown on the implant. Given the superior mechanical properties of the zirconia veneer, the shape and thickness of the veneers were modified chairside to have a harmonious anterior curve and a better aesthetic rendering. After determining the colour of the resin cement, the temporary crown was put back in place.

Fig. 4. Virtual model.

After glazing and preparation of the bonding surfaces in the dental laboratory, the upper veneers were cemented according to the PANAVIA™ Veneer LC protocol. We ended the session by removing excess cement. An occlusion check and postoperative photos were taken after three days.

DISCUSSION

In this case, the dental veneers and the crown on the implant were produced using a KATANA™ Zirconia UTML disc. This type of zirconia has an yttrium oxide proportion of 5 mol%, leading to about 70 % cubic zirconia phase, and therefore a higher translucency than earlier generations of zirconia. With a translucency of 51 % (light transmission, illuminant: D65, specimen thickness: 1.0 mm. Source: Kuraray Noritake Dental Inc); this zirconia allows us to have remarkable optical properties (fig 5).

Fig. 5. Remarkable optical properties of the final restorations.

The patient chose color BL1 and requested a transparent incisal edge. For this reason, a cutback design of the zirconia (fig. 6) and porcelain layering was the technique of choice. Figure 7 shows the slight transparency in the incisal edge region of the new restorations. The zirconia veneers technique was chosen to avoid the color difference between the crown on the implant and the veneers. The pleasant aesthetic appearance and a harmonious smile are confirmed by the post-operative picture (fig 8). According to the manufacturer, the flexural strength of KATANA™ Zirconia UTML is 557 MPa, which is higher than that of lithium disilicate and feldspathic porcelains. As zirconia veneers will be more resistant to shear forces, it is possible to eliminate contact points that interfere during try-in or even safely modify the shape of the restorations in vivo. This is done with specific burs adapted to zirconia during different stages of the fittings according to the wishes of the patient⁴.

Fig. 6. Cutback design of the restorations.

Fig. 7. Slight transparency at the incisal edges of the restorations.

Fig. 8. Immediate post-operative picture.

In the present case, we were able to adjust the crown until we had a perfect anterior line. It was thus possible to optimize the inclination of the crown without replacing the dental implant, in just one week.

Given the significant shear resistance, the dental laboratory technician made zirconia dental veneers with an average thickness of 0.3 mm. Such a thin veneer requires less preparation of the dental tissue, which will be limited to enamel instead of extending into the dentin, where the adhesion value is lower due to its low chemical composition in minerals⁵.

The expected difficulty in bonding zirconia veneers is explained by the absence of a vitreous phase given the poor adhesion of the crystalline phase to the bonding cement. However, the desired surface modification can be achieved with a different procedure: tribochemical silica coating. It was used in the present case to improve the adhesion of the zirconia veneers to the resin cement system. Indeed, it was found in an in-vitro evaluation that the tribochemical preparation technique and the application of MDP provide an optimized adhesive interface⁶. In this study, dual-beam focused ion-beam technology followed by scanning electron microscopy were used to compare the resin/zirconia bonding interface with tribochemical preparation/MDP and the bonding interface between resin/zirconia without this preparation.

The tribochemical process consists of an aero-abrasion of the zirconia surface with particles coated with silica combined with a silane primer containing MDP. The phosphate ester groups of this silane bind to the surface oxides of the zirconia, and the methacrylate group makes covalent bonds with the resin matrix of the PANAVIA™ Veneer LC cement⁷.

In the present clinical cases, the KATANA™ Zirconia UTML veneers were abraded with silicon dioxide with the formula SiO2. As a primer, we chose CLEARFIL™ CERAMIC PRIMER PLUS (Kuraray Noritake Dental Inc.), because it contains the original MDP monomer, developed Kuraray Co., Ltd.⁸.

To clean the veneers before applying CLEARFIL™ CERAMIC PRIMER PLUS, KATANA™ Cleaner (Kuraray Noritake Dental Inc.) was used. The presence of saliva and residues from fittings can alter the interface with the resin cement, which presents a risk of bonding failure of Zirconia veneers⁹.

One of the most important challenges in this case was to be able to hide the greyish color of the implant abutment which was visible through the zirconia crown. To hide the gray of the abutment, a resin opaker was applied. These techniques combined with the PANAVIA™ Veneer LC white gave us an optimal result (figs. 9 and 10)¹⁰.

Fig. 9. Treatment outcome.

Fig. 10. New smile designed according to the individual desires of the patient.

CONCLUSION

KATANA™ Zirconia UTML veneers have better mechanical properties than conventional veneers, so that the zirconia veneers technique allows users to combine bridges, crowns and dental veneers without a noticeable difference in shade. It offers acceptable translucency and aesthetics according to our observation. The technique of bonding the zirconia veneers with PANAVIA™ Veneer LC combined with a tribochemical treatment and the application of MDP on the adhesion surfaces allowed for a secure bonding, while the dyschromia caused by the implant abutment was effectively concealed.

Dentist:

DR. BASSEM JAIDANE

Born in Sousse, Tunisia, on June 12, 1983, Dr. Bassem Jaidane obtained his Doctorate in Dental Medicine in 2010 at the Faculty of Monastir. He opened his own clinic in 2010, specializing in aesthetics and dental implants, as well as dental veneers. Omni-patrician and passionate about all areas of dentistry, he has also developed advanced knowledge in dental prosthetics: 3D design, ceramic layering, finishing and glazing of crowns, bridges and veneers…

Dr. Bassem Jaidane has therefore acquired a certain expertise on the different types of dental veneers, whether pressed ceramic veneers, machined veneers, layereded veneers with the cut-back technique and lumineers veneers, after having carried out numerous cases. in feldspathic and lithium disilicate veneers, Dr. Bassem Jaidane has become one of the pioneers of the technique of dental veneers on zirconia.

References

1. Restaurations esthétiques grâce à la technique du cut-back Par Fleur Nadal, Geoffrey Di Bacco, Julien Chesnot Publié le 01.06.2019. Paru dans L‘Information Dentaire n°23 – 12 juin 2019 (page 28-29).
2. Effects of ceramic layer thickness, cement color, and abutment tooth color on color reproduction of feldspathic veneers Christopher Igiel, Michael Weyhrauch, Barbara Mayer, Herbert Scheller, Karl Martin Lehmann PMID: 29379907 Int J Esthet Dent 2018;13(1):110-119.
3. Influence of Air-Particle Deposition Protocols on the Surface Topography and Adhesion of Resin Cement to Zirconia. Acta Odontol: Sarmento, H.R.; Campos, F.; Sousa, R.S.; Machado, J.P.B.; Souza, R.O.A.; Bottino, M.A.; Ozcan, M: Acta Odontol Scand . 2014 Jul;72(5):346-53.doi: 10.3109/00016357.2013.837958. Epub 2013 Oct 31.
4. Comparison of the Mechanical Properties of Translucent Zirconia and Lithium Disilicate:Kwon, S.J.; Lawson, N.C.; McLaren, E.E.; Nejat, A.H.; Burgess, J.O. J.Prosthet:: J Prosthet Dent . 2018 Jul;120(1):132-137. doi: 10.1016/j.prosdent.2017.08.004. Epub 2018 Jan 6.
5. The Success of Dental Veneers According To Preparation Design and Material Type:Yousef Alothman, Maryam Saleh Bamasoud: Open Access Maced J Med Sci. 2018 Dec 14;6(12):2402-408.doi:10.3889/oamjms.2018.353. eCollection 2018 Dec 20.
6. The Effect of Resin Bonding on Long-Term Success of High-Strength Ceramics: Blatz, M.B.; Vonderheide, M.; Conejo, J: J Dent Res 2018 Feb;97(2):132-139. doi: 10.1177/0022034517729134. Epub 2017 Sep 6.
7. Ultra-thin monolithic zirconia veneers: reality or future? Report of a clinical case and one-year follow-up: Rodrigo Othávio Assunção Souza, Fernanda Pinheiro Barbosa, Gabriela Monteiro de Araújo, Eduardo Miyashita, Marco Antonio Bottino, Renata Marques de Melo, and Yu Zhang :Oper Dent :2018 ;43(1) :3_11.doi :10.234/16-350-T.
8. Functional monomer impurity affects adhesive performance :Kumiko Yoshihara 1 , Noriyuki Nagaoka, Takumi Okihara , Manabu Kuroboshi, Satoshi Hayakawa, Yukinori Maruo, Goro Nishigawa, Jan De Munck, Yasuhiro Yoshida, Bart Van Meerbeek : Dent Mater : 2015 Dec;31(12):1493-501.doi: 10.1016/j.dental.2015.09.019. Epub 2015 Oct 28.
9. Effect of decontamination materials on bond strength of saliva-contaminated CAD/CAM resin block and dentin Kei Takahashi, Tomohiro Yoshiyama, Akihito Yokoyama, Yasushi Shimada, Masahiro Yoshiyama : Dent Mater J 2022 Jul 30;41(4):601-607. doi: 10.4012/dmj.2021-268. Epub 2022 Apr 13.
10. Masking ability of implant abutment substrates by using different ceramic restorative systems Pablo Machado Soares , Ana Carolina Cadore-Rodrigues , Maria Gabriela Packaeser , Atais Bacchi , Luiz Felipe Valandro , Gabriel Kalil Rocha Pereira , Marília Pivetta Rippe J Prosthet Dent 2022 Sep;128(3):496.e1-496.e8. doi: 10.1016/j.prosdent.2022.05.010. Epub 2022 Aug 16. Affiliations PMID: 35985853 DOI: 10.1016/j.prosdent.2022.05.010.

DENTAL ADVISOR Editor’s Choice and 2023 Preferred Product award recipient, quickly provides durable bond in a single procedure

CLEARFIL™ Universal Bond Quick has been named a 2023 Editor’s Choice by DENTAL ADVISOR, which evaluates dental products and equipment and publishes its findings annually. It has also received recognition as DENTAL ADVISOR’s Preferred Product this year in the category of Universal Bonding Agents. The 31 consultants who evaluated its application during 1,065 usages gave it the excellent overall rating of 98%.

CLEARFIL™ Universal Bond Quick is a single-bottle fluoride-releasing, universal adhesive with MDP monomer and amide monomer chemistry called rapid bond technology. This combination of the MDP monomer, which creates a strong chemical bond to hydroxyapatite, and newly developed hydrophilic amide monomer, which is highly hydrophilic, is responsible for fast chemical bonding and quick penetration into dental tissue. Because the amide monomer rapidly permeates dentin and enamel, it eliminates the need for long rubbing application of the adhesive into the dentin and reduces the wait time after application. After curing, the innovative amide monomer forms a moisture-resistant cross-linked polymer network.

As a result, the bonding is moisture-resistant and stable, with durable results. This method, which reduces application time without compromising bond strengths, sealing, or desensitizing, also reduces technique sensitivity.

A fast and versatile agent that bonds directly to dentin, enamel, metals, zirconia and lithium disilicate restorative materials, CLEARFIL™ Universal Bond Quick is suitable for bonding direct and indirect restoration and can be used for total-etch, selective-etch, or self-etch methods. When mixed with CLEARFIL™ DC Activator, CLEARFIL™ Universal Bond Quick becomes dual-cure and has universal use with both self- and dual-cured resin cements and core build-up resins. 

The practitioners evaluating the product commented on its ease in dispensing and placement, viscosity, suitability for all bonding procedures, and convenience. Among their remarks were: “Perfect viscosity. Ease of use and speed were great.” and “Great for replacement of silane to prime crowns for cementation with resin cement - will self-cure with the dual-cured resin.”

Honors such as Editor’s Choice that are conferred by US-based DENTAL ADVISOR were introduced to help busy practitioners make sense of the numerous new solutions indicated for less invasive techniques, standardized or simplified procedures, and better outcomes on a regular basis. DENTAL ADVISOR conducts its practice-based clinical evaluations and product performance tests shortly after product launch, and publishes results annually online to help potential users identify high-quality new dental materials and determine which among them are best suited to fulfill their individual requirements.