Clinical case by Dr. Frank Heldenbergh

The advancements in zirconia in contemporary dentistry nowadays allow for a wider range of applications, including in the anterior sector, and for chairside production using dedicated CAD/CAM systems. Even without a cutback, KATANA™ Zirconia Block (STML), combined with CERABIEN™ ZR FC Paste Stain (both Kuraray Noritake Dental Inc.), offer an extremely satisfactory aesthetic solution.

In the present patient case, the materials were chosen to replace old PFM crowns on the maxillary central incisors. The planned treatment was in accordance with the patient's wishes, and carried out in a single appointment.

CASE DESCRIPTION

The patient asked for a replacement of the existing crowns on the two maxillary central incisors (teeth 11 and 21, FDI notation). The porcelain-fused-to-metal (PFM) restorations had been in place for about thirty years (Figure 1). She desired aesthetic improvements and slight repositioning of these two teeth.

TREATMENT PLAN

In agreement with the patient, it was decided to perform the entire procedure in one appointment: removal of the existing crowns, digital impressions, production, and bonding of new restorations. The periodontium was healthy with no bleeding. The only uncertainty was whether the existing crowns were cemented onto inlay-cores or if they were Richmond crowns. A preliminary silicone impression was taken as a precautious measure: in case something unexpected prevented the new crowns from being bonded during the session, it would be easily possible to produce temporary crowns.

Fig. 1. Initial clinical situation.

TREATMENT

Using a diamond bur followed by a tungsten carbide bur, the existing crowns were removed, revealing that they indeed were Richmond crowns. Because the anatomy of the intra-radicular posts clearly contraindicates an attempt to remove these posts, it was decided to trim the crowns to transform them into inlay cores rather than risk further damage. The corono-peripheral preparations were reworked at the same time. One of the major challenges was related to the necessity of masking the metal of the transformed coronal-radicular reconstructions. Luckily, the space available was sufficient for the production of full zirconia crowns with a significant thickness (Figure 2). The target shade of the crowns was chosen in consultation with the patient (Figure 3).

Fig. 2. Situation after removal of the existing restorations.

Fig. 3. Shade determination using a shade tab: A2 was the appropriate shade.

Subsequently, impressions were taken using and intraoral scanner, the virtual models were checked and the crowns designed, considering the patient's request to have her two incisors slightly retracted (Figures 4 and 5).

Fig. 4. Virtual models of the patient’s teeth with the newly designed crowns, revealing the space available for a slight retraction.

Fig. 5. Designing of the two crowns.

The two crowns were milled from KATANA™ Zirconia Block 14Z A2 (Figure 6). A quick reminder: unlike lithium disilicate, zirconia prosthetic parts cannot be tried in immediately after milling, as they are around 20 percent larger than their final size after sintering. Final sintering was performed within about 18 minutes using the furnace SINTRA CS (ShenPaz Dental Ltd). After this process, the crowns may be tried on to check their fit, shape, shade and optical integration.

Fig. 6. Milled crowns in the CAD/CAM blocks.

For finishing of the restorations, different options are available. In this case, we decided not to limit ourselves to mechanical polishing of the prosthetic parts, as zirconia does not fluoresce like natural teeth. To add fluorescence as an optical feature, the surface was lightly stained and glazed with CERABIEN™ ZR FC Paste Stain (Figure 7).

Fig. 7. Crowns in the furnace after staining and glazing with liquid ceramics.

After firing, the two incisor crowns were tried in again using a try-in paste corresponding to the chosen resin cement system (PANAVIA™ V5, Kuraray Noritake Dental). In this way, the final appearance was simulated to validate the shade of the cement. The intaglio surfaces of the crowns were then sandblasted before applying CLEARFIL™ CERAMIC PRIMER PLUS as the restoration primer. The prepared teeth were treated with KATANA™ Cleaner (Kuraray Noritake Dental Inc.) to decontaminate the surface from proteins in saliva and possibly blood. Those clean surfaces are ideal for bonding. After thorough rinsing and drying, PANAVIA™ V5 Tooth Primer (containing MDP monomer for bonding with the hydroxyapatite and metal of the preparation) was applied according to the manufacturer’s instructions (Figure 8).

Fig. 8. Selected cementation system and try-in.

Subsequently, PANAVIA™ V5 Paste was applied into the first crown, which was then seated, followed by tack curing (brief photopolymerization for three to five seconds), excess removal and final light curing from all sides.

The procedure was then repeated for the second maxillary central incisor. The result instantly satisfied the patient, both in terms of aesthetics (adaptation, position of the new crowns, mimicry) and the comfort provided (Figures 9 and 10).

Fig. 9. Crowns immediately after placement.

Fig. 10. Aesthetically pleasing and comfortable result.

At a recall after four months, soft tissue conditions were ideal and the patient was happy with the outcome (Figures 11 to 13). The selected zirconia had nice optical properties, masking of the metal posts was successful and the natural surface texture contributed its share to a nice overall picture. The retracted position of the teeth was also perceived positively by the patient, while comfort and function were excellent.

DISCUSSION

Although lithium disilicate has so far been considered the material of choice for prosthetic work in the anterior region, zirconia is nowadays proving to be an extremely satisfactory alternative from every point of view: milling, strength, aesthetics, assembly (among other things, no hydrofluoric acid is required for bonding). KATANA™ Zirconia Blocks (STML) with a multi-layered colour structure in a single 4Y-TZP zirconia block, combined with CERABIEN™ ZR FC Paste Stain, offer a remarkable solution. This applies to treatments around the replacement of existing crowns as well as first-line treatments with less invasive preparations (verti-prep) than those required by other types of ceramics.

Fig. 11. The patient’s smile at a recall after four months.

Fig. 12. Great optical integration.

Fig. 13. Natural surface texture contributing to success Control pictures after four months taken by Emmanuel Charleux.

Dentist:

FRANK HELDENBERGH

Dr. Frank Heldenbergh graduated with a Doctor of Dental Surgery degree from the University of Reims in 1988.Driven by a passion for prosthetics, he pursued further specialization as a Prosthetic Resident at the UFR Odontology of Reims from 1990 to 1992. Dr. Heldenbergh’s dedication to advancing dental practices led him to join the Board of the Academy of Adhesive Dentistry in 1999. His commitment to this field has been unwavering, and he currently serves as the Vice President of A.D.D.A.-R.C.A.

Recognized for his expertise in ceramic veneers, inlays and onlays, Dr. Heldenbergh supervised practical work for the Paris Odontological Society from 2000 to 2018, shaping the skills of many aspiring dentists. His influence extended to the A.D.F. Congress, where he supervised practical work on ceramic veneers from 2000 to 2016. In 2017, he was the Head of Practical Work at A.D.F., a role that allowed him to further contribute to the advancement of dental education and practices. In 2018, he was the Head of Practical Work for ceramic veneers at the Paris Odontological Society.

Recognizing the importance of technology in modern dentistry, Dr. Heldenbergh pursued a University Degree in CAD/CAM from Toulouse in 2022. This addition to his qualifications highlights his dedication to staying at the forefront of dental innovation.

DELICATE BALANCE BETWEEN COSTS AND AESTHETICS IN DENTAL LAB

When you are a lab owner striving to achieve high-end results using modern digital techniques, the initial investment in CAD/CAM technology is significant, followed by ongoing costs for expendable items such as milling tools and blanks. That cost can be reduced by selecting universal, high-quality materials.

Undoubtedly, zirconia stands out as one of the most popular materials on the market. From an inventory perspective, however, lab owners often find themselves purchasing multiple discs of the same shade and thickness. The reason is that they need to meet all requirements for strength and aesthetics in different settings – enabling them to cover all kinds of restorations and deliver excellent patient outcomes.

UNIVERSAL SOLUTION FOR DENTAL LABS

At Kuraray Noritake Dental Inc., we take pride in not only developing the first-ever multilayer zirconia, KATANA™ Zirconia ML, but also in our commitment to delivering the highest quality materials that we can.

KATANA™ Zirconia YML, our latest addition to the KATANA™ Zirconia line-up, exemplifies this dedication and offers universal applicability. The universal feature is based on the fact that KATANA™ Zirconia YML disc not only offers colour gradation, but also impressive flexural strength and translucency gradation, with maximum values of up to 1,100 MPa and 49 % translucency, respectively.

INHOUSE PRODUCTION - THE PATH TO HIGH QUALITY ZIRCONIA DISC

Like all our zirconia offerings, KATANA™ Zirconia YML begins its journey to the dental lab in our Japanese facility where raw zirconia powder undergoes special treatment process before the addition of essential components.

Once the material has undergone this thorough initial stage, it progresses to the pressing and pre-sintering phase to form the disc. Every detail is carefully calculated, managed and controlled. This phase of the process takes several days, underscoring our goal to achieve the most aesthetic product.

HIGH-SPEED SINTERING PROGRAM: 54 MINUTES

The unique powder formulation and refinement process, as well as the pressing and pre-sintering technique, is the key to allow our customers to realize restorations of up to three-unit bridges without any compromise in terms of aesthetics or mechanical properties using the 54-minute high-speed sintering* process.

This high quality, lengthy production process results in an exceptionally dense material, which once sintered, goes on to deliver a high strength, high aesthetic final restoration.

HIGH PRECISION SHRINKAGE AND STABLE CTE VALUES FOR EXCEPTIONAL FIT

Outstanding deformation stability during the sintering procedure, contributes to the stability during the final sintering process in the dental laboratory, providing for an exceptional fit of large-span bridges and other restorations.

MULTI-LAYERED STRUCTURE AND EASE OF POSITIONING OF RESTORATIONS IN THE BLANK

To enhance aesthetic qualities, all KATANA™ Zirconia YML discs are designed using ratios rather than fixed measurements of different layers in the multi-layered structure. This means that regardless of the disc's thickness, there is always a consistent ratio of 35 % of raw material that constitutes the translucent enamel zone. Hence, discs with an increased height, which are typically used for the production of larger restorations, will always offer sufficient space in the enamel zone, while smaller discs are optimized for smaller restorations.

ONE DISC. ALL INDICATIONS.

These qualities empower dental lab owners to deliver a wide range of restorations. The material is suitable for single crowns to full-arch structures, for full-contour designs to conventional frameworks, using a single material without compromising on aesthetics: KATANA™ Zirconia YML. For finishing, we offer a well-aligned portfolio of solutions designed for internal and external staining, micro-layering and full layering.

EXPLORE KATANA™ Zirconia YML: WEALTH OF RESOURCES, CLINICAL CASES AND FAQS

Visit our website to discover more about KATANA™ Zirconia YML. You will find useful materials such as brochure, technical guide, in-depth technical information.

Would you like to see the material in action – browse the blog section of our website that offers a variety of clinical cases and articles by world-renowned experts showcasing and proving the versatility and aesthetics of KATANA™ Zirconia YML.

*The material is removed from the furnace at 800°C. A furnace with a configurable KATANA™ Zirconia YML firing program is required.

Case by Andreas Chatzimpatzakis

Observe and copy: This is the key to nature-like dental restorations. There are many optical effects, colour transitions and morphological details in natural teeth that need to be taken in and understood – and replicating them is only possible for those who know exactly how their materials work. Once these skills are acquired, however, they enable a dental technician to produce their restorations as truly beautiful copies of nature. Even when restoring a single maxillary central incisor, the technique delivers outstanding – or inconspicuous - outcomes, as revealed by the following example.

Using high-quality, translucent and gradient-shaded zirconia frameworks and porcelains, the layering technique does not have to be highly complicated. Two bakes and a number of selected effect liquids, internal stains and porcelains are usually sufficient for outcomes that exceed expectations.

CASE EXAMPLE

In the present case, a young male patient had a quite opaque crown on his maxillary right central incisor that needed to be replaced. During shade selection in the dental laboratory (Fig. 1), it was observed that the cervical third of the adjacent central incisor is lighter than the rest. Its shade in other areas corresponded to B4 on the VITA classical A1-D4^® Shade Guide. Hence, it was decided to use a somewhat lighter material for the framework and darken the restoration especially in the middle and incisal areas with internal stains.

The concrete plan was to mill a coping made of KATANA™ Zirconia STML (Kuraray Noritake Dental Inc.) in the shade A3, characterize it with Esthetic Colorant (both Kuraray Noritake Dental Inc.) and sinter the piece (Figs 2 to 4). In the following layering procedure including just two bakes, a combination of internal stains and selected porcelains (CERABIEN™ ZR, Kuraray Noritake Dental Inc.) was applied as illustrated in Figures 5 to 12. Figures 13 to 17 display the result on the model, minor adjustments during try-in and the final treatment outcome.

Fig. 1. Shade selection. The cervical third of the adjacent central incisor is lighter than usual compared to the middle and incisal areas.

Fig. 2. Coping made of KATANA™ Zirconia STML in the shade A3.

Fig. 3. Intensification of some shade characteristics of the multi-layered blank using Esthetic Colorant in the shades Grey (middle) and Blue and Grey (incisal area).

Fig. 4. Coping after sintering.

Fig. 5. Colour map for internal staining, using CERABIEN™ ZR Internal Stains.

Fig. 6. Result of the use of Shade Base Stain Modifier Fluoro to increase the fluorescence and internal staining as planned.

Fig. 7. Application of Opacious Body OBA2, …

Fig. 8. … Translucent Tx …

Fig. 9.: … and Luster CCV-2.

Fig. 10. Crown after the first bake.

Fig. 11. Crown after the application of CERABIEN™ ZR Internal Stains: A+, Aqua Blue 2, White mixed with Cervical 2 (ratio: 30/70) for the cracks, and Cervical 2.

Fig. 12. Application of Luster LT1 to finalize the shape.

Fig. 13. Finished crown after the second bake on the model.

Fig. 14. Evaluation of the surface texture: Observing and copying the surface details is as important as the imitation of the shade characteristics.

Fig. 15. Minor texture adjustments during try-in.

Fig. 16. Final restoration in place after cementation with PANAVIA™ V5 (Kuraray Noritake Dental Inc.).

Fig. 17. Treatment outcome.

CONCLUSION

Mastering the art of observing natural teeth is the key to lifelike restorations. It allows a dental technician to develop a deep understanding of shade and morphology, which is – apart from knowing the selected materials very well – the only talent needed to reach a high level of excellence. Those who are observant and take in every detail with their eyes can be sure that their mind will understand and their hands will automatically follow.

Dental technician:

ANDREAS CHATZIMPATZAKIS

Andreas graduated from the Dental Technology Institute (TEI) of Athens in 1999. During his studies he followed a program at the Helsinki Polytechnic Department of Dental Technique, where he trained on implant superstructures and all ceramic prosthetic restorations. As of 2000, he is running the ACH Dental Laboratory in Athens, Greece, specialized on refractory veneers, zirconia and long span implant prosthesis. In 2017 Andreas visited Japan where he trained under the guidance of Hitoshi Aoshima, Naoto Yuasa and Kazunabu Yamanda and become International Trainer for Kuraray Noritake Dental Inc..

Case by Martin Laurik, MDT

There are so many different restorative materials out there and so many design and finishing concepts available that it often seems difficult to select the best option for a specific case. Using an allrounder like KATANA™ Zirconia YML can facilitate decision making: It is a great choice for single- to multi-unit restorations, works on teeth and implants alike, and can be adapted to individual needs by selecting a suitable design concept and adequate finishing technique. In this way, it is even possible to solve aesthetically challenging cases as the one illustrated below.

Initial situation and temporization

This patient was in need for treatment after the loss of her maxillary right central incisor and the placement of an implant in this region. As a replacement of the restorations on the other three maxillary incisors was necessary as well, it was decided to produce four crowns made of the same material – KATANA™ Zirconia YML. For aesthetic evaluation of the restorations’ length, angulations and shape in the mouth and a functional test drive, the crowns were digitally designed in full contour and milled from PMMA in the determined tooth shade A2 (Fig. 1).

Fig. 1. Full-contour PMMA crowns on the master cast.

Design, milling and effect dyeing of the zirconia crowns

Once the appearance and functional aspects of the temporary restorations were approved by the patient and the restorative team, the definitive crowns were produced. Their design was based on the full-contour design of the temporaries; however, a facial reduction of 0.6 mm was carried out by the software to create space for individualization with a small layer of veneering porcelain. The crowns were then milled from a KATANA™ Zirconia YML disc in the shade A1 – approximately one shade lighter than the determined tooth shade. To mask the uneven colour from the tooth stumps and the implant abutment, the intaglio of the crowns was treated with Esthetic Colorant in the shade Opaque. Some individual and intensified colour effects on the vestibular surface were also created with Esthetic Colorant.

Internal staining and porcelain layering

To slightly adjust the chroma and lightness, a first layer of CERABIEN™ ZR Internal Stains was added, followed by a wash bake. After the application of a first layer of CERABIEN™ ZR porcelains (Body, Enamel and Translucent) and baking (Fig. 2) – the central incisors received a layer of A1B, the lateral incisors a mixture of A1B and A2B (slightly darker to provide for a better match with the canines) with LT1, LT Natural completing the picture – additional internal staining was carried out (Fig. 3). The final layer of CERABIEN™ ZR luster porcelains (LT1, ELT2 used on the convex line angles to achieve an external reflection) was added and fixed in a fourth bake (Fig. 4).

After adjustments and very rough polishing, a self-glaze firing programme was selected (firing temperature 915 °C, holding time 5 seconds). On the highly polished incisal and palatal parts of the crowns and for contact point adjustment, CERABIEN™ ZR FC Paste Stain Glaze was applied and fixed with the same bake. The finished crowns on the model are shown in Figure 5, while Figure 6 displays the final treatment outcome.

Fig. 2. Crowns milled from KATANA™ Zirconia YML with a facial cutback of 0.6 mm after individualization with Esthetic Colorant, sintering, internal staining and the application of a first layer of porcelain.

Fig. 3. This picture shows the subtle internal stain adjustment to the ceramic mostly on the incisal part.

Fig. 4. Crowns prior to final shape adjustments and polishing.

Fig. 5. Finished crowns on the model.

FINAL SITUATION

Fig. 6. Treatment outcome.

Easy approach to beautiful restorations

The presented approach is a relatively easy way of producing highly aesthetic anterior restorations. Using an allrounder zirconia combined with a few selected effect liquids, internal stains and luster porcelains, it is possible to achieve a great optical integration even in a situation where teeth and implants need to be restored. The natural shape and surface texture of the restorations plays an important role in this context, as does the base material – a naturally shaded, highly translucent zirconia.

Dentist:

MARTIN LAURIK, MDT

Martin started working as a dental technician in 2014. In the time since, he never stopped training and learning from renowned colleagues. Continuing education courses focused on dental ceramics and occlusion in the functional concept of Slavicek. Fascinated by the beauty of natural teeth, developing an understanding of their complexity and learning how to mimic nature’s design as closely as possible has always been his primary goal, while he is well aware that there is still a lot to be learned and explored on the road to excellence.

Presented by Kuraray Noritake Dental Inc.

Highly translucent multi-layered zirconia developed by a proprietary material and manufacturing method from Japan

CURRENT STATUS AND FUTURE PROSPECTS OF ZIRCONIA RESTORATIONS

In this issue, we asked Markus B. Blatz, Professor at the University of Pennsylvania, USA, Aki Yoshida (Gnathos Dental Studio) and Naoki Hayashi (Ultimate Styles Dental Laboratory), both dental technicians active in the USA and international instructors for Kuraray Noritake Dental Inc., to give their views on zirconia restorations and their outlook for the future.

WITH THE INTRODUCTION OF ZIRCONIA, THE MAINSTREAM OF PROSTHETIC TREATMENT HAS SHIFTED FROM METAL CERAMICS¹ TO ZIRCONIA CERAMICS². WHAT CHANGES HAVE OCCURRED WITH THE INTRODUCTION OF ZIRCONIA?

Blatz: My mentor for my first Ph.D. in dental materials was in the group that developed lithium disilicate and glass-infiltrated alumina. Therefore, I have seen the evolution of dental ceramic materials, including zirconia, which is the subject of this presentation, up close and personal.

Early zirconia was white, opaque, and not as esthetic as today. However, there is no doubt that zirconia ceramics were much more esthetic than metal ceramics. At the same time, however, we often heard the opinion that bilayer zirconia ceramic restorations were problematic, and this provoked much discussion. We conducted a large study in collaboration with a Boston laboratory to compare more than 1,000 posterior porcelain-fused-to-metal crowns and 1,100 posterior porcelain-fused-to-zirconia crowns and found no difference in chipping or fracture rates after about seven years. This proves that bilayer zirconia ceramics are safe when used with the proper veneering materials and the proper sintering and cooling protocols. The fact that zirconia became established as it is today is a major change for dentistry in general.

Yoshida: I also switched from metal ceramics to zirconia ceramics, and now I don't use metal anymore. It used to take a lot of time and effort to invest and cast metal, observe it with a microscope, and fit it. Considering the recent rise in metal prices, it has also become more cost-effective. In addition, I am allergic to metal and have a skin rash every time I have a prosthetic processed, so the shift to zirconia ceramics as the mainstream prosthetic is a welcome change. Of course, the use of zirconia has also improved esthetics. The translucency of zirconia is the greatest advantage that metal does not have.

Hayashi: Yes, that's right. The big advantage of zirconia is that if the abutment is not strongly discolored, it no longer needs to be treated with an opaquer. It was not easy to control the reflection of light from the operative tooth when fabricating metal ceramics. In addition to the esthetic advantage, the prosthetic space can be thinner than that of metal ceramics.

1. Metal ceramics: Prosthetic made of metal frame with porcelain.
2. Zirconia ceramics: Prosthetic made of zirconia frame with porcelain.

THE YEAR 2023 MARKED THE 10^TH ANNIVERSARY OF THE FIRST MULTI-LAYERED ZIRCONIA – KATANA™ ZIRCONIA ML. SINCE THEN, HOW DO YOU THINK HIGHLY TRANSLUCENT MULTI-LAYERED ZIRCONIA HAS REVOLUTIONIZED PROSTHETIC DEVICE MANUFACTURING?

Yoshida: I feel the ability to extend the zirconia frame to the occlusal surface and the incisal edge is the greatest advantage of using highly translucent multilayered zirconia. This allows us to provide crowns of both esthetics and strength, even for patients with para function. I have also made a zirconia Maryland bridge using highly translucent multi-layered zirconia, and it is doing very well. There are some cases where it is not possible to use zirconia, but still, it is wonderful to have a wider range of options.

Blatz: Many people still have the impression that zirconia cannot be bonded to tooth structure, but resin cement can be used to bond zirconia to tooth structure after proper pretreatment. Clinical studies of resin-bonded zirconia bridges have shown very high success after 10 or 15 years. Currently, resin bonding is recommended for very thin, highly translucent zirconia, rather than cementation. However, it should be added that this requires the dentist and technician to understand the proper bonding technique for zirconia.

In addition, Kuraray Noritake Dental's multi-layered zirconia has revolutionized monolithic zirconia without the need for veneering porcelain. However, this has also resulted in the need for dental technicians to shift to a different approach: instead of building up the restoration as with veneering ceramics, esthetic features are created on the outer surface in each case.

Maxillary 6 anterior monolithic crowns (Markus B. Blatz)

Fig. 1a and b: Initial examination.

Fig. 1c: Simulation of final prosthetic restoration.

Fig. 1d: Completed prosthetic on model (monolithic crown using KATANA™ Zirconia STML).

Fig. 1e and f: Final restoration (Dr. Julian Conejo and Sean Han, CDT).

Two cases of Maryland bridge and laminate veneers and a mandibular canine single crown implant superstructure (Aki Yoshida)

Fig. 2a and b: Case 1: A case of a congenital defect of a lateral incisor was restored with a Maryland bridge. Since the proximal and distal width of the defect was greater than the central incisor, a non-prep veneer was fabricated on the central incisor to balance the proportions. KATANA™ Zirconia STML was used for the Maryland bridge. Note the harmony between the zirconia frame extended to the incisal edge and the transparency of the laminate veneers made of Super Porcelain EX-3™ on the central incisors. This case demonstrates the characteristics of zirconia, which combines strength and esthetics.

Fig. 3a to c: Case 2: A case of a screw-retained crown restoration of an implant placed in a mandibular canine tooth. Extension of the zirconia frame from the entire lingual side to the incisal margin prevents fracture of the porcelain by the screw access hole edges and canine guides. KATANA™ Zirconia STML provides natural transparency even when zirconia is exposed at the incisal edge.

Maxillary 4 Anterior teeth implant bridge (Naoki Hayashi)

Fig. 4a to f: Implant bridge of maxillary four anterior teeth using implants placed in the maxillary bilaterallateral incisors as abutments and maxillary bilateral central incisorsaspontics. The lingual side is fully backed with zirconia and the labial side is minimally layered with CERABIEN™ ZR.

Hayashi: Indeed, the highly translucent multilayered zirconia has expanded the possibilities of monolithic crowns. For patients with high occlusal forces, monolithic crowns are suitable in terms of strength, and with the use of highly translucent multilayered zirconia, it is possible to achieve a certain level of esthetics with monolithic crowns. In fact, some patients are happy with it. However, at least in the current situation, we believe that if patients and dentists want high-end esthetics, then porcelain buildup is necessary, and monolithic crowns are only an option.

Blatz: The variety of options available is the advantage of zirconia. The dentist and the technician can work together to provide the best possible outcome for the patient.

Yoshida: In terms of options, Kuraray Noritake Dental's zirconia can be sintered in a short time (approximately 90 minutes) in addition to the normal sintering time (7 hours) using a zirconia raw material and manufacturing method developed by Kuraray Noritake Dental, which is an advantage in that it can be used for immediate restorations, remanufacturing and other unexpected situations.

FINALLY, DO YOU HAVE A MESSAGE FOR THE NEW GENERATION OF DENTISTS AND DENTAL TECHNICIANS?

Blatz: I encourage my students and colleagues to always do their best. This leads to good results, makes you happy, and makes you feel satisfied with your life. Some people only try to get rich, but just accumulating wealth is never happiness. The second is to keep an open mind. Nowadays, we are inundated with information through social media.

Some of it is very stimulating and wonderful, but there is also a lot of it that is wrong. On the other hand, there are those who believe that everything one leader says must be done. I would like to tell them, "Make sure you get your information from reliable sources, and then choose reliable information for yourself. Dentistry is changing, so let's keep an open mind. The most important thing is that the patient is ultimately satisfied with the results.

Hayashi: I would like the future generation to learn more about tooth morphology, occlusion, and fit. Color is the essence of the quality of the final prosthetic device, but we need to learn tooth morphology, occlusion, and fit before we learn color. We are all about creating a prosthetic device that will function in the patient's mouth for the long term, and that is our goal. There will be new technologies and materials in the future, but their essence will never change. I hope that you will always remember what is important in your clinical practice. This is why basic knowledge of anatomy and function is necessary.

Yoshida: New technologies and materials will continue to emerge. But human teeth will not change. The most important thing is to provide the best possible care to the patient. I hope that you will accumulate such experiences, and that when you reach the end of your life, you will be able to say that you are glad you chose this profession.

Thank you very much for the meaningful discussion today.

Source: QDT Vol.49/2024 April
The magazine may not be printed from the web and may not be forwarded
No reproduction or reprinting allowed

Dentists:

KATANA™ Zirconia YML offers an unmatched blend of aesthetics and mechanical properties, but also provides for cost and time efficiencies.

Recognised for its strength and density at point of manufacture, the material delivers incredible hardness in its green state. This offers the fully validated opportunity to make adjustments in morphology directly after milling.

These qualities, along with its strength and translucency once sintered, deliver the possibility to produce a wide range of high aesthetic indications. KATANA™ Zirconia YML has set a new benchmark in prosthetic dentistry.

It provides dental technicians with a material that is truly universal with no compromises required.

KATANA Zirconia YML in a Nutshell

KATANA Zirconia YML represents a pinnacle of zirconia technology. With its multi-layered structure, it offers a seamless gradation of colour, strength and translucency that mimics natural teeth, making it an ideal choice for the entire indication spectrum.

The material's unique composition allows for high-speed sintering (up to 3-unit bridges), which significantly reduces production time without sacrificing optical or mechanical properties.

Colour Gradation and Physical Properties

The colour gradation of KATANA Zirconia YML is designed to replicate the natural colour transition of human teeth, from the dentin core to the translucent enamel surface.

This combined with the material's impressive flexural strength of up to 1,100 MPa and translucency of up to 49%, enables the production of restorations that are virtually indistinguishable from natural dentition.

Applications and Advantages of KATANA Zirconia YML

KATANA™ Zirconia YML's versatility extends to a wide range of indications, including crowns, veneers, inlays, onlays, and bridges of all sizes. With its strong body and highly translucent enamel layer, it offers exactly the properties required for an unlimited indication range.

Positioning of restorations in KATANA™ Zirconia YML discs is extraordinarily easy. The reason is that the gap between the lowest flexural strength found in the enamel area and the highest flexural strength found in the lowest body layer is comparatively small. Moreover, the Body Layer 1 that is found adjacent to the enamel layer already offers a flexural strength that is higher than the 800 MPa requested for bridges with four or more units. Consequently, the material is classified as a Class 5 zirconia and users are on the safe side whenever they place their long-span restorations in the middle of the blank.

Positioning of long-span restorations in the middle of the disc.

Revolutionizing Sintering with High-Speed Capabilities

One of the groundbreaking aspects of KATANA Zirconia YML is its compatibility with high-speed sintering protocols. This capability allows dental laboratories to expedite the production process, delivering high-quality restorations in a fraction of the time traditionally required. Sintered during normal working hours at daytime, small restorations can be finished within hours, while the sintering load at night is reduced automatically. Great option not only for rush cases!

The high-speed sintering process does not compromise the material's optical or mechanical properties, maintaining its aesthetics and strength.

Recommended Finishing Techniques for Optimal Results

KATANA Zirconia YML is a beautiful and aesthetic material in its own. Therefore, when it comes to finishing, CERABIEN™ ZR FC Paste Stain is a great option.

KATANA Zirconia YML: A Testament to Innovation in Dental Materials

KATANA Zirconia YML stands at the forefront of dental material technology, offering outstanding aesthetics, strength, and efficiency. Its introduction has marked a significant advancement in the capabilities of dental technicians, allowing for the creation of restorations that truly mimic the beauty of natural teeth in a fraction of time.

As the dental industry continues to evolve, KATANA Zirconia YML remains a testament to the relentless pursuit of excellence in restorative dentistry.

For more detailed information on KATANA Zirconia YML, including technical guide, FAQs and Clinical cases, visit Kuraray Noritake Dental's YML dedicated page.

Interested in articles, user experience or clinical cases using KATANA Zirconia YML? Check the blog section of our website! 

Mathias Fernandez Y Lombardi

EU Scientific Manager
Dental Ceramics & CAD/CAM Materials
Kuraray Europe GmbH

With PANAVIA™ SA Cement Universal and KATANA™ Zirconia

By using PANAVIA™ SA Cement Universal and its proprietary dual-monomer technology, you can now simplify the bonding of restoration to implant abutments without the use of separate primers or silane. Independent research has confirmed this new dual-monomer technology does not sacrifice adhesion or durability on glass-based ceramics or zirconia. The technique, in this case study, is for custom fabricated abutment & KATANA™ Zirconia YML crown, however, the basic technique on the treatment of the abutment and restoration may be used with any implant restoration combination as long as the proper surface treatments for type of material is followed.

INITIAL FIT OF ABUTMENT & RESTORATION

Basic technique on the treatment of the abutment and restoration.

Fig. 1. Check Initial Fit of Abutment & Restoration: abutment & crown margins should be checked to ensure proper fit.

Fig. 2. Protect base of implant with putty or light-cure block-out resin. The base of the implant should be covered so that it is not air abraded accidentally.

Fig. 3. Abrade titanium abutment with 50 μm alumina oxide powder.

Fig. 4. Clean abutment with KATANA™ Cleaner: Apply KATANA™ Cleaner by rubbing each area for 10 seconds.

KATANA™ Cleaner is a universal cleaner that is indicated to clean metal, zirconia & glass-based restorations. It is also an intra oral cleaner that may be used on dentin and enamel.

TREATMENT OF KATANA™ Zirconia RESTORATION WORKFLOW

Bonding to zirconia has been proven to be durable in research going back to the 1990’s with the original MDP adhesive monomer in the PANAVIA™ resin cements. The three requirements to bonding zirconia are:

1. Air abrade zirconia with 50 μm alumina oxide powder.
2. Clean zirconia
3. Apply an MDP-Based Primer or resin cement. PANAVIA™ SA Cement Universal contains the original MDP that was developed & patented in 1981 by Kuraray Dental.

Fig. 1. Air abrade KATANA™ Zirconia at 14-58 psi.

Fig. 2. Dispense & mix PANAVIA™ SA Cement Universal (it is available in automix or handmix formulations).

Fig. 3. Apply PANAVIA™ SA Cement Universal to the abutment or inside the crown.

Fig. 4. Seat restoration on abutment.

Fig. 5. Remove excess resin with a dry micro-applicator or brush.

Fig. 6. You may light-cure the margins after cleaning up all excess resin. If you fully cure excess resin, It can be difficult to remove. If difficult to remove, change curing time or distance with your light.

Fig. 7. Leave restoration on abutment to self-cure fully for approximately 10 minutes at room temperature.

Fig. 8. Final check of custom abutment KATANA™ Zirconia YML crown on model.

Dentist:

JEAN CHIHA

Technician Jean Chiha CDT, Santa Ana, CA USA

Mr. Chiha is the owner of North Star Dental Laboratory and Milling Center, Santa Ana, CA, and has served as President of the Dental Lab Owners Association of California since 2013. He is a 1985 graduate of Institut Dento Technic, a private dental technology school in France. Mr. Chiha lectures internationally on dental communication and case planning. Jean lectures around the world on a variety of topics and has carved out a niche with his extensive knowledge of zirconia. Affectionately referred to as “Mr. Katana” due to his involvement in the creation of the material.

Case report by Dr. Wissam Dirawi, DDS

During the last decade, zirconia has increasingly established itself as the material of choice in oral prosthodontic rehabilitation. Its great mechanical and inert properties are the main reason for this trend. Since the introduction of multi-layered zirconia blanks more than ten years ago, the optical properties have been improved dramatically. The multi-layered zirconia used nowadays (e.g. KATANA™ Zirconia YML from Kuraray Noritake Dental Inc.) offers well-balanced mechanical properties, translucency and colour. It allows dental technicians from all over the world to produce aesthetic full-contour restorations that are merely stained.

Even in the anterior region, stained monolithic restorations may be an option. Factors such as the age of the patient, the internal colour structure of the adjacent dentition, the number of teeth to be restored (one versus all four or six maxillary anterior teeth), the aesthetic demands of the patient and financial aspects should be taken into account in the material selection process. In the case described below, full-contour zirconia was selected for several reasons.

BACKGROUND

The 71-year-old female presented in the clinical due to aesthetic problems in the maxillary anterior region. Oral hygiene was good and the patient was a non-smoker. Infraposition of the existing implant-based crown (Nobel Biocare Brånemark RP fixture) in the position of the right central incisor (tooth #11 according to the FDI notation) was evident. Moreover, gingival retraction was observed on the maxillary right lateral incisor (tooth #12), while the left lateral incisor (tooth #22) has a major composite filling with discolouration. The patient expressed the desire to adjust the gingival level differences and to restore the four maxillary incisors with all-ceramic crowns for optimal aesthetics.

Fig. 1. Initial situation: Frontal view.

Fig. 2. Initial situation: Facial view.

Fig. 3. Initial situation: Occlusal view of the maxilla.

Fig. 4. Initial situation: Occlusal view of the mandible.

MATERIAL SELECTION

Due to the decision to restore all four anterior incisors, monolithic zirconia was a suitable material option. It would allow the team to obtain the desired results within the financial framework. In order to meet the aesthetic demands of the patient, provide for the required mechanical properties and allow for proper masking of the underlying structures, KATANA™ Zirconia YML was selected. It offers colour, translucency and flexural strength gradation throughout the multi-layered blank.

TREATMENT PROCEDURE: FROM PREP TO TEMPORIZATION

In order to design the indirect restorations, a digital impression was taken with an intraoral scanner and the data was transferred to the dental laboratory Teknodont in Malmoe, Sweden. There, a digital wax-up was created. After patient approval, a matrix was produced and sent to the clinic. Here, the old restorations were removed and the three maxillary incisors (all but the one replaced by an implant) prepared for full coverage restorations. A healing abutment was placed on the implant and a temporary bridge produced chairside using the matrix and Protemp 4 Temporization Material (3M) in the shade A3. Subsequently, a gingivectomy was carried out with a ceramic burr (Ceratip, Kt.314.016 – KOMET) in the buccal aspect of the left central and lateral incisor.

Fig. 5. Chairside-produced temporary in the patient’s mouth.

After the patient’s approval of the aesthetics, phonetics and function of the temporary restoration, the situation was captured with an intraoral scanner again. This allowed the team to duplicate the shape of the construction. Based on the acquired data, a new set of splinted temporary crowns made of PMMA (HUGE Multilayer PMMA) in the shade A3 was milled in laboratory. They were placed to allow the patient to further evaluate the aesthetic appearance and function for a couple of weeks. The patient was happy with the phonetics, function and appearance of the crowns, which were merely slightly too bright in comparison to the adjacent teeth, and approved the shape for the production of the permanent restorations.

Fig. 6. Printed model …

Fig. 7. … with splinted PMMA crowns.

Fig. 8. Lab-made temporary restorations.

Fig. 9. Long-term temporary in place: Lateral view from the right.

Fig. 10. Long-term temporary in place: Frontal view.

Fig. 11. Long-term temporary in place: Lateral view from the left.

FINAL RESTORATIONS: PRODUCTION AND CEMENTATION

Based on the dataset of the temporary restorations, four separate crowns – one implant and three tooth-based – were designed in full contour. Without any anatomical reduction, the restorations were milled from KATANA™ Zirconia YML. Based on the evaluation of the temporary restoration, the shade selected this time was A3.5. CERABIEN™ ZR FC Paste Stain was used for external staining and glazing of the surface. Still in the laboratory, the implant-based crown was cemented to the gold-shaded titanium abutment (Elos Medtech) with PANAVIA™ V5 (Kuraray Noritake Dental Inc.) in the shade opaque for an improved masking effect.

While the abutment crown was screwed onto the implant and the screw hole closed with composite, the three tooth-based crowns were placed using PANAVIA™ SA Cement Universal (Kuraray Noritake Dental Inc.).

Fig. 12. Final restorations on the model.

Fig. 13. Intraoral situation prior to restoration placement.

CONCLUSION

Multilayered zirconia is a suitable material for many clinical situations. Due to the availability of modern types of highly translucent, multi-layered blanks, it is possible to produce aesthetic outcomes even when using the material monolithically – not only in the posterior region, but also in the aesthetic zone in some indications. The present case shows that very good results and patient satisfaction can be obtained. And due to outstanding mechanical properties, these outcomes may be expected to last for a long time.

Fig. 14. Immediate treatment outcome: Facial view.

Fig. 15. Immediate treatment outcome: Frontal view.

Fig. 16. Immediate treatment outcome: Occlusal view.

Dentist:

WISSAM DIRAWI

Dr. Wissam Dirawi, Malmoe, Sweden. DDS.
Specialist in Oral Prosthodontics and Senior Adviser at Aqua Dental.

2000 Master´s degree in dentistry.
2000 - 2018 General Dentist in public dental care and private practice.
2011 - 2018 Part-time teacher and researcher at Malmö University, Faculty of Dentistry.
2018 Specialist in Oral Prosthodontics. Senior clinical adviser. Lecturer.

References

- Alfadhli R, Alshammari Y, Baig MR, Omar R. Clinical outcomes of single crown and 3-unit bi-layered zirconia-based fixed dental prostheses: An up to 6- year retrospective clinical study: Clinical outcomes of zirconia FDPs. J Dent. 2022 Dec;127:104321.
- Le M, Papia E, Larsson C. The clinical success of tooth- and implant-supported zirconia-based fixed dental prostheses. A systematic review. J Oral Rehabil. 2015 Jun;42(6):467-80.
- Alammar A, Blatz MB. The resin bond to high-translucent zirconia-A systematic review. J Esthet Restor Dent. 2022 Jan;34(1):117-135.
- Sadowsky SJ. Has zirconia made a material difference in implant prosthodontics? A review. Dent Mat 2020; 36: 1–8.
- Mazza LC, Lemos CAA, Pesqueira AA, Pellizzer EP. Survival and complications of monolithic ceramic for tooth-supported fixed dental prostheses: A systematic review and meta-analysis. J Prosthet Dent 2022; 128: 566–74.
- Passia N, Mitsias M, Lehmann F, Kern M. Bond strength of a new generation of universal bonding systems to zirconia ceramic. J Mech Behav Biomed Mater. 2016; 62:268–274.
- Sailer I, Makarov NA, Thoma DS, Zwahlen M, Pjetursson BE. All-ceramic or metal-ceramic tooth- supported fixed dental prostheses (FDPs)? A systematic review of the survival and complication rates. Part I: Single crowns (SCs). Dent Mater 2015; 31:603-623.
- Pjetursson BE, Sailer I, Makarov NA, Zwahlen M, Thoma DS. All-ceramic or metal-ceramic tooth- supported fixed dental prostheses (FDPs)? A systematic review of the survival and complication rates. Part II: Multiple-unit FDPs. Dent Mater 2015; 31:624–639.

By Manabu Suzuki, Director of Dental Division, Kuraray America, Inc.

Kiyoko Ban, a prominent figure in the dental technology field, has made a lasting impact as a researcher, developer, and founder of Noritake Dental business (Fig. 1). Renowned for her contributions to dental porcelains like Noritake's CZR and EX-3, and KATANA™ Zirconia, Ms. Ban stands as a pivotal force in the global advancement of dental technology, earning her the esteemed reputation of developer and marketer within the dental technology community.

After completing her university education in Nagoya, Ms. Ban initially assisted in her family's gas station business. However, driven by a desire for a career change, she enrolled in a newly established dental technician college in Nagoya at the age of 30. Her aspiration was to enter a field where gender distinctions held no sway, offering the potential for worldwide recognition based on technical mastery.

In 1977, a college-sponsored tour to American dental laboratories ignited Ms. Ban's dream to work in the United States. However, she delved into research across various fields such as chromatology (the science of color), ceramics and metals, finding a newfound passion for research over clinical work after graduation because she was offered a "Curriculum Chief" position from the college when she graduated (Fig. 2).

Fig. 2. Ms. Ban, a curriculum chief at the Dental Technicians College, devoted her evenings to material research.

Fig. 3. In the 1990s, Ms. Ban actively engaged in promoting EX-3 through sales efforts in Italy.

Her teaching career spanned from the age of 34 to around 40, during which she pioneered porcelain training sessions for technical improvement and arranged lectures over weekends by famous speakers such as Masahiro Kuwata.

At the age of 40, she resigned teaching career and pursued her research career. The opportunity to conduct full-scale experiments led her to the discovery of a company with advanced ceramic technology "Noritake Co., Limited", renowned for its tableware. In 1986, Cusp Dental Supply, a research institute, was established by Ms. Ban in Nagoya, focusing on the development of materials for PFM crowns. The commercialization of Super Porcelain AAA (EX-3) in 1987 marked a significant milestone, addressing issues prevalent in porcelain materials of that time, such as cracks, greening, and fluorescence.

She began traveling all over Japan and around the world to sell the products she had developed and went on to develop new products that were needed by dental technicians worldwide (Fig. 3). She continued to develop new products such as CZR, CZR Press, and KATANA™, the world's first multilayer zirconia.

Ms. Ban has been actively involved in mentoring students and graduates seeking opportunities to work overseas. During summer vacations, she took students and professionals interested in working abroad to countries like Australia, Germany, and the United States. The aim was to visit dental clinics, dental technician schools, and laboratories, fostering exposure and learning in an international context.

Simultaneously, Ms. Ban delved into researching non-precious dental technology. Inspired by her exposure to the term "non-precious" during her time in the United States, she anticipated its potential in Japan. Her research presented at lectures and events highlighted the shift in the landscape as the price of gold surged, rendering precious alloys containing significant amounts of gold impractical for PFM crowns.

As the demand for their developed products grew, the need for global acceptance became apparent. In 1990, Cusp Dental Research was established in Manhattan, New York, marking Ms. Ban's foray into establishing a company overseas. Despite the unfamiliarity with legal procedures and the challenges of setting up a foreign company, Ms. Ban, driven by determination, overcame these hurdles. The establishment of the company in the United States expanded their presence internationally Fig. 4).

Fig. 4. Capturing the essence of ISC 1996 - the International Symposium on Ceramics in Orlando, FL..

Noritake Dental Supply Co., Limited was established in 1998 by the Noritake Co., Limited, which aimed to further expand its dental business. Despite the absence of a capital relationship with Noritake at the time of establishing the research laboratory, Ms. Ban played a key role in joint research efforts with Noritake. Then she was invited to this company as the position of president, owning 60% of the stock, while Noritake held 40% (Fig. 5).

Besides Noritake Dental business, she continued expansion with the establishment of a dental laboratory in Boston in 1995. Despite the challenges posed by the September 11, 2001 World Trade Center incident, they acquired their building in Boston, integrating their New York laboratory into the Boston operations.

Ms. Ban's tenure as president of Noritake Dental Supply persisted until 2009, but organizational changes following the merger with Kuraray in 2011 led to her transition into an advisory role (Fig. 6). Despite the shift in responsibilities, her commitment to the dental technician profession remained steadfast.

Fig. 5. Noritake Dental Supply Inc Inauguration Party, 1998.

Kiyoko Ban's path encapsulates not just a career but a legacy in the field of dental technology. From her early struggles in a tooth carving class to establishing and expanding international laboratories, Ms. Ban's story is one of determination, innovation, and a deep-rooted commitment to advancing the dental technician profession.

Fig. 6. A scene from Ms. Ban’s retirement celebration as Noritake Dental Supply president, surrounded by esteemed dental technicians from around the world.

Available Now!

Have you ever produced a zirconia restoration without obtaining the outcome you expected? Most dental technicians probably have. The bad thing is that aesthetic flaws such as colour deviations or white spots and technical issues like cracks can occur and require remakes. The good thing is, however, that those problems are usually avoidable. Do you know how?

We would like to show you – in the new KATANA™ Zirconia Troubleshooting Handbook we just completed. On 30 pages, this handbook summarized the most important facts about modern zirconia-based restorative materials, their selection, the KATANA™ Zirconia line-up and, finally, possible aesthetic or technical problems, their origin and solutions to overcome them.

Let us assume that the beauty of your restorations is limited due to a lack of translucency. By looking up the problem “lack of translucency”, you will find a compact, well-structured overview of possible causes and adequate solutions. The recommendations include selecting dry instead of wet milling, abstaining from sandblasting the restoration surface and checking of the sintering parameters, quality of the sintering beads and position of the restoration in the furnace. For more details, problems and solutions, download the handbook!

DOWNLOAD NOW