429 Too Many Requests

Case by Dr. Kristine Aadland.

Fig. 1. Preparation.

The patient’s old PFM bridge (shown here) was removed, and the existing preps for teeth #6 and #8 were modified with a medium chamfer with smooth and rounded edges to accommodate a 3-unit KATANA™ Zirconia bridge. There was no abutment for tooth #7, as that space serves as the pontic. Tooth #9 was similarly prepared to receive a single-unit KATANA™ crown.

Fig. 2. Define Restorations.

To begin, each restoration type is defined in the CEREC software, as the design mode (Biogeneric Individual), material type (KATANA™ Zirconia Block), and milling device (CEREC MC XL).

Fig. 3. Digital Impression.

A digital impression of the upper arch was performed using CEREC Primescan.

Fig. 4. Restoration Design.

The patient did not like the size of her centrals and wanted them smaller. She also didn’t like that her smile was slanted/canted. While designing, it really helps to use the patient’s old smile as a reference. This is why I used Bioindividual when designing the restorations, and added a BioCopy folder in the acquisition screen. I can ghost over the previous smile and readily see where I am.

Fig. 5. Restoration Design: Occlusal.

The BioCopy design function is also utilized to ensure a correct occlusal profile.

Fig. 6. Milling.

A KATANA™ Zirconia Block for bridge (14Z L) was used for the 3-unit bridge, and a KATANA™ Zirconia 12Z single-unit block was used for the single crown. The bridge block mills out in about 18 minutes, which is the fastest-milled chairside bridge block currently available.

Fig. 7. Characterization & Sintering.

Kuraray Noritake CERABIEN™ ZR FC Paste Stain and Glaze Kit was used for characterizing. The colors are very natural and it is not simply a metal oxide like other stains, but actually adding porcelain, giving the restorations more vitality. The oven cycle is quick at approximately 10 minutes, which means multiple fires are easy to do without excess time.

Fig. 8. Seating & Final Smile.

PANAVIA™ SA Cement Universal and CLEARFIL™ Universal Bond Quick were used for cementation and bonding. I love the ease of use and clean-up with PANAVIA™ SA Cement Universal, and its MDP monomer creates a strong chemical bond to the tooth structure and zirconia. CLEARFIL™ Universal Bond Quick has a quick technique without reducing bond strengths, releases fluoride and has a low film thickness. I simply rub CLEARFIL™ Universal Bond Quick into the tooth for a few seconds and air dry. There is no need to light-cure, since it cures very well with PANAVIA™ SA Cement Universal. The patient was very happy with the results. She loved that she no longer saw metal margins, and her smile was much more uniform and lifelike.

DR. KRISTINE AADLAND

Using KATANA™ Cleaner and PANAVIA™ SA Cement Universal

Case by Dr. Richard Young

Fig. 1. HF etch and try-in complete.

Fig. 2. Dispense KATANA™ Cleaner into mixing well.

Fig. 3. Rub for 10 seconds, then rinse and dry.

Fig. 4. Rub for 10 seconds, then rinse and dry. KATANA™ Cleaner contains MDP based surfactant that breaks down blood and saliva - removing contamination.

Fig. 5. Apply cement directly onto restoration (glass ceramic, zirconia, metal or composite resin).

Fig. 6. PANAVIA™ SA Cement Universal contains MDP and LCSi monomers, providing for durable bonding even to lithium disilicate restorations.

Fig. 7. Tack-cure for 2-5 seconds.

Fig. 8. Tack-curing results in nice gel-like-state and excess is removed with ease.

FINAL SITUATION

Fig. 9. Final situation.

Dentist:

DR. RICHARD YOUNG

By PhD. M. Inokoshi.

INTRODUCTION

Kuraray Noritake Dental Inc. is a manufacturer with a long history and wealth of experience in the field of producing dental materials, including bonds, cements and ceramics. The all-ceramic restorations market, including that for zirconia products, has been growing rapidly around the world since the beginning of the 2000’s. In response to this trend, we have established an integrated production system that can be used to manufacture a wide range of dental zirconia products in-house, from powder to discs.

When we develop new zirconia products, we carefully analyze the characteristics of dental zirconia that are actually demanded by users in the clinical setting and, based on the results of our analysis, we craft new products with these clinically needed characteristics. In our first efforts we focused on developing a dental zirconia that would have a natural tooth color after sintering. We launched “KATANA™ Zirconia”, our first dental zirconia product to span all the VITA^* Classical A1-D4 shade Guide, in 2007. Following in 2013, using our original manufacturing method, we developed and launched “KATANA™ Zirconia” ML (Multi-Layered), a multi-layered zirconia product that produces smooth color gradations like those of natural teeth, avoiding sharp color transition between layers. Then, in 2015, we also released “KATANA™ Zirconia” UTML (Ultra Translucent Multi-Layered) and STML (Super Translucent Multi- Layered). These are highly translucent, multi-layered zirconia products that became other versions of our multi-layered zirconia family. We are one of the pioneering manufacturers of dental zirconia, and as such, we promise ourselves that we will keep on delivering excellent highly-esthetic dental zirconia products to the dental market now and into the future.

^*VITA is a trademark of VITA Zahnfabrik, Bad Sackingen, Germany.

Recent advancements in dental technology have made it possible to use zirconia as a prosthetic material across a wide variety of dental applications, from large-sized implants where great mechanical strength is required, to treatment in the anterior region, where esthetics are of the utmost importance. The material characteristics needed, however, differ from one treated case to another. Many dental zirconia suppliers respond to these therapeutic requirements by offering various types of dental zirconia that feature different levels of mechanical and esthetic properties. This requires dentists and dental technologists in clinical settings to select, from a wide range, the type of zirconia that will be more better appropriate to treat the case they are facing at any given moment. This means it is necessary for each clinic to keep in stock many types of dental zirconia materials with different characteristics, in order to meet the requirements of the wide variety of possible case parameters.

Several dental material manufacturers have responded to these circumstances by offering dental zirconia disc products that have combinations of multiple layers with different levels of translucency and mechanical strength. They claim these products make materials available that can be used to fabricate a wide range of restorations. These products, however, can have serious shortcomings. Some require laborious manufacturing work, tailored to the fabrication of the particular restoration. Others do not include the required high-strength zirconia layer that makes it possible to fabricate a bridge. These products, therefore, may provide no assurance of providing the mechanical strength recommended by ISO for the manufacture of certain restorations. A market need arose for dental zirconia products that could be used easily and safely for the fabrication of a wide range of restorations.

In response to this need, at Kuraray Noritake Dental Inc., we have developed and released “KATANA™ Zirconia” YML(YML), a new type of dental zirconia material that provides the blend of excellent performance variables provided by the “KATANA™ Zirconia” Multi-Layered series. With its well-balanced performance, the YML can be indicated for the fabrication of a wide range of restorations, from large sized ones requiring great mechanical strength to anterior crowns that require a high level of translucency In this paper, we would like to describe YML’s features and the technology behind it. We will also present comparative data collected by Masanao Inokoshi, a professor in the Department of Gerodontology and Oral Rehabilitation at Tokyo Medical and Dental University, Graduate School of Medical and Dental Sciences, on YML and a similar product from the competition.

FEATURES OF THIS PRODUCT AND THE TECHNOLOGY BEHIND IT

Short sintering time

YML can be baked satisfactorily in a short period of time, thanks to our innovative technology. In addition to the conventional sintering schedule of about 7 hours, and even the 90-minute schedule, we have also made it possible to shorten the sintering time further, to a remarkable 54 minutes^*.

^*The material is removed from the furnace at 800°C / 1472°F. Up to 3-unit bridges.

Excellent translucency and great mechanical strength

A YML disc consists of four layers: one Enamel and three Body layers. The top Enamel layer (35% of the total thickness: 750 MPa^*1) is composed of the same zirconia material as “KATANA™ Zirconia” STML, which is highly acclaimed for its excellent translucency. The three Body layers ((1): 1,000 MPa^*1, (2): 1,100 MPa^*1 and (3): 1,100 MPa^*1) that lie below the Enamel layer are made from a new type of zirconia material. Body layer (1) is an intermediate layer that has the desirable translucence of STML. It includes, however, a well-balanced combination of translucency and mechanical strength suitable for the treatment of cases, such as those requiring bridges, which demand these notable characteristics. Body layers (2) and (3) provide the high level of mechanical strength of “KATANA™ Zirconia” HTML suitable for the fabrication of large-sized restorations, along with an improved level of translucency. With its well-balanced combination of translucency and mechanical properties, provided by taking advantage of multiple zirconia ceramics, YML is a product that meets the demand for highly esthetic products. It is suitable for the fabrication of the whole range of restorations, from single crowns to bridges.

^*1 : According to ISO 6872: 2015, three-point bending test.

Multi-layer gradation

Kuraray Noritake Dental Inc. released our first multi-layered zirconia product in 2013. Subsequently, the company launched zirconia products very much appreciated for their smooth transition of color gradation, much like that of natural teeth. We use our own innovative pressing method to manufacture YML. It smooths the change of colors between layers, which provides the desirable feature of a very smooth and natural color transition.

Reduced deformation after sintering

In general, dental zirconia shrinks during the sintering process by about 20 percent in 2 dimensions (50 percent in volume). If shrinkage cannot be controlled adequately, it becomes difficult to fabricate restorations that fit precisely into complicated abutments or margin lines. The shrinkage of zirconia materials varies subtly from one production lot to another, even when the same raw material is used. We appropriate raw material control such as raw material crushing etc., using different sintering shrinkage rates for different production lots. In view of the fact that the sintering shrinkage of zirconia materials requires delicate control, it is not hard to understand that shrinkage control is even more difficult when different zirconia materials are combined into one disc. If the shrinkage rates of the layers of a zirconia disc differ, the restoration will necessarily be deformed during shrinkage. Many users voiced particular concerns about dimensional stability when they were asked about using zirconia discs (which require high precision) for the fabrication of implants. Kuraray Noritake Dental Inc. has an integrated production system that is used to manufacture zirconia products in-house, from the design and manufacture of zirconia powder as a raw material to final products, thus making it possible for us to control the shrinkage rate of zirconia with great accuracy. For this reason, we are able to use zirconia materials with stably controlled shrinkage rates to manufacture YML, even though it consists of multilayers made up of different zirconia materials. This minimizes deformation of restorations after shrinkage.

RESULTS OF A VERIFICATION OF THE PHYSICAL PROPERTIES OF YML AND A REVIEW OF ITS CLINICAL ADVANTAGES

To verify the physical properties of YML, the translucence, mechanical strength and crystalline structure of YML and ZirCAD Prime (Ivoclar Vivadent) were analyzed and compared with one another at the Tokyo Medical and Dental University. Among the physical properties examined, this paper focuses especially on data on the translucency and mechanical strength of each product.

Data on translucency:

Different alphabets indicate a definite difference between groups.

Data Courtesy of PhD. Masanao Inokoshi, Tokyo Medical and Dental University.

The translucency of ZirCAD Prime was significantly higher than that of YML, when a comparison was made at the Enamel layer. This is probably because Prime contains almost no pigment in the Enamel layer, in order to bring out the brightness (whiteness) of the zirconia itself. By contrast, YML contains some pigment, so the product can deliver an optimal level of brightness in the clinical setting. That is, it seems that the addition of pigments leads to a difference in translucency between YML and Prime.

Data collected at Kuraray Noritake Dental on the relative translucency of YML and Prime

Total light transmittance (%) (Illuminant: D65; test specimens with a diameter of 30 mm, and a thickness of 1 mm) Raw material in YML’s Enamel layer (no coloring agent): 49% Prime’s Enamel layer: 49%.

Regarding the layers lying beneath the Enamel, such as the Transition and Body layers, YML was found to be more translucent than Prime. It can be concluded that YML is sufficiently translucent even beneath the layers lying beyond the Enamel layer. This makes it possible to fabricate prostheses with natural tooth colors, when used in combination with an Enamel layer that is suitably adjusted to provide the optimum color.

Mechanical strength data as results of four-point bending test:

Different alphabets indicate a definite difference between groups.

Data Courtesy of PhD. Masanao Inokoshi, Tokyo Medical and Dental University.

The Enamel layer of YML had a significantly greater bending strength than that of Prime. On the other hand, when the bending strength of the Body layers was compared, Prime’s Body layer was the strongest. The three YML Body layers ((1), (2) and (3)) had bending strength values of more than 850 MPa^*2, and there were no significant differences in bending strength among Prime’s Body layer and YML’s Body layers ((1), (2) and (3)).

The results revealed that while YML has small differences in bending strength among the Enamel layer and the three Body layers, Prime has clearly different levels of bending strength between the Body layer and the other two layers. YML’s Body layers (including the intermediate layer) have such a high level of mechanical strength that it is quite feasible to use it to fabricate highly reliable prostheses.

^*2 : According to ISO 6872: 2015, four-point bending test.

LAYERED DESIGN CONCEPT

The guide for fabricating large restorations using YML states the requirement that at least 50% of the connector cross-section should be positioned in the bottom (lower part) of the disc. This means that generally you can meet the requirement of the guide by positioning the restoration at the center of the disc’s four layers. Guides or advices of restoration fabrication for using zirconia discs available in the market may sometimes be complicated to position the restoration as specified in the guide or to position the piece as specified by the guide, which makes it difficult to fabricate a highly esthetic restoration that makes use of the Enamel layer’s better translucency.

When we developed YML, Kuraray Noritake Dental kept in mind that the fabrication guide must be practical, as well as easy. That’s why YML was designed with a sufficiently thick Enamel layer that permits a high level of esthetics for any type of restoration that might be fabricated.

CONCLUSION

“KATANA™ Zirconia” YML is our new zirconia disc product, which features a well-balanced combination of mechanical strength and esthetics. It has been developed by using our innovative zirconia manufacturing technology, as well as bringing together the essence of the development and production technology of multi-layered zirconia discs. We hope YML will be one of the options of choice for zirconia materials available to dentists and dental technologists who need to use multiple zirconia materials for various applications or who have concerns about the mechanical strength and esthetic properties of the zirconia materials they are currently using.

YML LINEUP

Case by Keisuke Ihara, RDT, Yohei Sato, DMD, PhD and Tsurumi University School of Dental Medicine.

MINIMAL CUT-BACK DESIGN

Accommodate esthetics and function, achieves natural color and surface texture due to thin porcelain layer.

Step 1.  Teeth preparation.

Step 2.  Inner crowns were placed on the abutments.

Step 3.  Zirconia Frame (KATANA Zirconia HTML A1) cut-back designed for incisal frame.

Step 4.  Application of Cerabien™ ZR (CZR) for making base color and firing.

Step 5.  Application of Internal Stain and firing.

Step 6.  The final restoration and inner crown parts.

Step 7.  Post-operative view.

How did experts think about the effectiveness of MDP through the years? You can read about it below.

“In particular, primers and composite cements that contain 10-methacryloyloxy-decyl-dihydrogen-phosphate (10-MDP) resulted in a relatively high bond strength and durability.”

N. Nagaoka et al: “Chemical interaction mechanism of 10-MDP with zirconia” Nature, Sci Rep. 2017; 7: 45563.

“For most zirconia-bonding techniques, the use of an “MDP-containing primer” also appeared to have a positive effect.”

B. van Meerbeek et al: “Meta-analyis of Bonding Effectiveness to Zirconia Ceramics” J. Dent. Res. 93(4), 2014, 329-334.

“Based on the direct interaction of the phosphate-ester group of MDP with the metal oxides at the zirconia surface, a relatively favourable bonding effectiveness was recorded.”

B. van Meerbeek et al: “Durable bonding to mechanically and/or chemically pre-treated dental zirconia”, J. Dent. 41 (2013) 170-179.

“Clinical data provide strong evidence that air-abrasion at a moderate pressure in combination with using phosphate monomer containing primers and/or luting resins provide long-term durable bonding to glass-infiltrated alumina and zirconia ceramic under the humid and stressful oral conditions.”

M. Kern: “Bonding to oxide ceramics-laboratory testing versus clinical outcome”, Dent. Mater. Vol. 31 (1), 2016, 8–14.

“A high and reliable resin bond to alumina and zirconia ceramics was also achieved with airborne particle abrasion and by using a phosphate monomer (MDP) containing resin composite luting cement.”

M. Özcan et al: “Effect of surface conditioning methods on the bond strength of luting cements to ceramics”, Dent. Mat. 19, 2003, 725-732.

“In the present study, the use of the MDP-containing bonding/silane agent resulted in significantly higher bond strengths before and after long-term storage and thermal cycling with two types of resin luting agents.”

M.B. Blatz et al: “In vitro evaluation of shear bond strengths of resin to densely-sintered highpurity zirconium-oxide ceramic after long-term storage and thermal cycling”, J. Prosth. Dent. 91, 2004, 356-362.

“Dental zirconia can no longer be considered unbondable to tooth tissue (…) This also indicates that Al2O3 sandblasting is best followed by a chemical pre-treatment with an MDP containing primer.”

M. Inokoshi et al: “Meta-analysis of Bonding Effectiveness to Zirconia Ceramics”, J. Dent. Res. 93(4): 329-334, 2014.

“Airborne-particle abrasion of zirconia surface is one of the most-investigated methods, provides good bond strength to zirconia when combined with phosphate ester monomer.”

M. Ferrari et al: “Effect of surface pre-treatments on the zirconia ceramic–resin cement microtensile bond strength”, Dent. Mat. 27, 2011, 1024-1030.

“The data of the present work confirm the assumption of another study [13], that MDP bonds chemically to zirconia ceramic.”

C.H.F. Hämmerle et al: “Effect of thermocycling on bond strength of luting cements to zirconia ceramic”, Dent. Mat. 22, 2006, 195-200.

“An acidic adhesive monomer such as MDP shows chemical bonding to zirconia-based ceramics. The phosphate ester group of the acidic monomer results in chemical bonding to metal oxides (MxOy, oxidized surface of base-metal alloys), zirconia-based ceramics and other ceramics.”

J.M. Powers et al: “Guide to Zirconia Bonding Essentials”, New York, NY: Kuraray America Inc, 2009, 1-13.

Multiple porcelain layering with Internal Stain technique

In 2015, Kuraray Noritake Dental Inc. launched the new KATANA Zirconia UTML and STML. With this outstanding multi-layered zirconia you can reach high level of esthetic in less steps than usual working steps of layering porcelain technique. Just mill and sinter. Due to great properties of this new material, you will get a high esthetic and natural like result. On the other hand, there are many works existing in clinical situation that only professional handmade can achieve the highest esthetic level. Multiple porcelain layering and Internal Stain technique have bigger possibility sometime to show beyond natural.

Fig. 1. Pre-operative photo.

Fig. 2. After preparation.

Fig. 3. Checking the fit of Zirconia Frameworks on model.

Fig. 4. After 1st baking of OB as washbake.

Fig. 5. After wash-baking, using with Internal Stain A+ on the margin area to make a natural cervical color from Zirconia.

Fig. 6. Applying Opacious Body (OBA1) considering with mamelon structure. And apply Body A2B to make high chrome area on cervical area.

Fig. 7. After baking Opacious Body (OBA1).

Fig. 8. After applying Body porcelain (A2B), using wit Cut-Back method to make a space for applying Enamel & Luster porcelains.

Fig. 9. Applying Enamel porcelain (E2) and Luster Porcelain (T Blue) for explaining translucent gradation on the edge of mamelon.

Fig. 10. Applying E2 for making White-band and LT1 for making incisal edge. Considering of porcelain shrinkage after baking, apply 13% bigger than final shape.

Fig. 11. After baking.

Fig. 12. Internal Stain application Applying A+ for cervical color and White for make white spots on incisal area.

Fig. 13. Applying E2 on Cervical area and LT1 for covering surface. And using with E2 on the edge of incisal to make Hallow Effect.

Fig. 14. After baking and morphological correction. Then self-glazing.

Fig. 15. End result.

Fig. 16. Post-operative photo.

Courtesy: Kanare Technical Center in Japan

Case by Sung Bin Im, MDC, CDT and Sergio R Arias, DDS, MS

MINIMAL CUT-BACK DESIGN

KATANA multi-layered zirconia allows me to achieve great esthetic and functional outcomes on high risk patients.

Step 1. Titanium Abutments (#7, 9) were placed on the solid model.

Step 2. Zirconia Frame (KATANA Zirconia HT10) cut-back designed to minic anatomical dentin structure and incisal frame.

 
Step 3. Application and firing of Cerabien™ ZR (CZR) to achieve target shade and incisal effect.

Step 4. Completion of Internal Stain firing.

Step 5. Completion of Luster and Clear Cervical layering.

Step 6. Surface detail check.

Step 7. Post-operative view.

Virtual Kick-Off KATANA Zirconia Symposium

Lecture 1 of 3, Prof. Dr. Beuer
Watch how Prof. Dr. Beuer explains his experience with the new material. Two in one: Combining High Strength and High Translucent Zirconia.

Lecture 2 of 3, MDT Rondoni + MDT Rossi
Watch the recording of the KATANA Zirconia YML Online Symposium on July 3rd 2021, the second lecture plus hand-on which details the experience of MDT Rondoni and MDT Rossi with this new material.

Lecture 3 of 3 + Q&A, MDT Nondas Vlachopoulos
Mister Vlachopoulos deepdives in to a full procedure executed with the new material and demonstrates how liquid ceramics compliment the material establishing a very high-end aesthetic result.

Case by Dr. Shoji Kato of Takanawa Dental Office, Japan

1. After preparing the abutments

An anterior bridge made of crown and bridge resin has become dislodged. The abutments are vital teeth.

2. Prosthesis

A PFZ bridge with a frame fabricated using KATANA™ Zirconia HT12.

3. Application of Try-in Paste

Evaluate the shade of the cement before cementation.

4. Try-in

After checking the cement’s shade, rinse the prosthesis and tooth surface with water to remove Try-in Paste.

5. Pretreatment of the prosthesis (A)

Sandblast the prosthesis (at 0.3 to 0.4 MPa), clean with an ultrasonic cleaner for 2 minutes, then dry.

6. Pretreatment of the prosthesis (B)

Apply CLEARFIL™ CERAMIC PRIMER PLUS and blow dry with air.

7. Pretreatment of the abutments (C)

Apply Tooth Primer, allow it to react for 20 seconds, then blow dry with air.

8. Application of Paste

Use Universal.

9. Placement of the prosthesis

After placement, remove excess cement using a piece of gauze, a small brush, etc.

10. Light-curing

Light-cure the entire surface of the prosthesis, including the margins.

11. Final polymerization

Make sure the prosthesis is left in place, unmoved, for 3 minutes.

Article by Peter Schouten.

We've seen them all: composite fillings that function present clinically, but are too ‘visible’ to be called aesthetic. The much-used term 'white filling' is probably quite appropriate here. In comparison to the tooth structure, these restorations are too opaque, or sometimes too transparent.

How much better would it be if the composite helped to create a seamless transition between tooth structure and composite? The so-called 'blending'.

But what enables this 'blending’ of composite and tooth structure to occur? The secret lies in utilizing the right mix of different filler particles and resins which give CLEARFIL MAJESTY™ ES-2 its light-diffusing properties. By varying the proportion of light-diffusing particles and the amount of pigment, it's possible to create composites with differing light-scattering properties and opacities. The most opaque variants contain more light-diffusing particles and more pigment. The more translucent ones contain obviously less.

All CLEARFIL MAJESTY™ ES-2 variants have the same filler content. This is important, as it means that the mechanical properties of all the CLEARFIL MAJESTY™ ES-2 variants are the same. The more translucent variants contain more barium glass than the more opaque variants. A higher barium glass content can lead to a less workable composite. With CLEARFIL MAJESTY™ ES-2, this is not the case. Kuraray has mastered the silanization process to such an extent that all variants, whether translucent or opaque, have the same filler amount, without compromising on workability.

Light diffusion test

Light diffusion properties are easy to see if the thin composite slices are placed on a black and white paper background and then held a few millimeters above the paper. Composites with high diffusion properties make the black strip virtually invisible. They blend in more readily with their surroundings.